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1,4-bis(benzimidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene
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1,4-bis(benzimidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene
CAS:338451-18-6 分子式:C26H26N4 分子量:394.51144
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产品名称:1,​1'-​[(2,​3,​5,​6-​Tetramethyl-​1,​4-​phenylene)​bis(methylene)​]​bis[1H-​benzimidazole]​
其他名称:pbbimb;1,​4-​Bis(benzimidazol-​1-​ylmethyl)​-​2,​3,​5,​6-​tetramethylbenzene
CAS:338451-18-6
结构信息
分子式 C26H26N4 分子量 394.51144
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Ag2(pbbimb)​3]​ [r1]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Su, Cheng-Yong; Cai, Yue-Peng; Chen, Chun-Long; Zhang, Hua-Xin; Kang, Bei-Sheng; J. Chem. Soc., Dalton Trans. 2001, (4), 359-361, DOI: 10.1039/b010118o ; Coordination-​directed assembly of trigonal and tetragonal molecular boxes encapsulating anionic guests
2) Su, Cheng-Yong; Cai, Yue-Peng; Chen, Chun-Long; Kang, Bei-Sheng; Inorg. Chem. 2001, 40(10), 2210-2211, DOI: 10.1021/ic0014282 ; Unusual Noninterpenetrating (3,​6) Topological Network Assembled by Semirigid Benzimidazole-​Based Bridging Ligand
3) Su, Cheng-Yong; Cai, Yue-Peng; Chen, Chun-Long; Smith, Mark D.; Kaim, Wolfgang; Zur Loye, Hans-Conrad; Journal of the American Chemical Society 2003, 125(28), 8595-8613, DOI: 10.1021/ja034267k ; Ligand-​Directed Molecular Architectures: Self-​Assembly of Two-​Dimensional Rectangular Metallacycles and Three-​Dimensional Trigonal or Tetragonal Prisms
4) Zhang, Qian; Zhang, Jianyong; Yu, Qiong-Yan; Pan, Mei; Su, Cheng-Yong; Cryst. Growth & Des. 2010, 10(9), 4076-4084, DOI: 10.1021/cg100742c ; Ring-​Opening Isomerization Based on the 3-​Connecting Node: Formation of a 0-​D M2L3 Cage, 1-​D Loop-​and-​Chain, and 2-​D (6, 3) Network

5) Liu, Qing-Xiang; Hu, Ze-Liang; Yu, Shao-Cong; Zhao, Zhi-Xiang; Wei, Deng-Che; Li, Hui-Long; ACS Omega 2018, 3(4), 4035-4047, DOI: 10.1021/acsomega.8b00205 ; NHC Pd(II) and Ag(I) Complexes: Synthesis, Structure, and Catalytic Activity in Three Types of C-​C Coupling Reactions

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1,4-bis(benzimidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene
1,4-bis(benzimidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene