产品名称:1,1'-[(2,3,5,6-Tetramethyl-1,4-phenylene)bis(methylene)]bis[1H-benzimidazole]其他名称:pbbimb;1,4-Bis(benzimidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene CAS:338451-18-6
结构信息
分子式 |
C26H26N4 |
分子量 |
394.51144 |
性状照片 |
|
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Ag2(pbbimb)3] [r1]
表征图谱
参考文献
1) Su, Cheng-Yong; Cai, Yue-Peng; Chen, Chun-Long; Zhang, Hua-Xin; Kang, Bei-Sheng; J. Chem. Soc., Dalton Trans. 2001, (4), 359-361, DOI: 10.1039/b010118o ; Coordination-directed assembly of trigonal and tetragonal molecular boxes encapsulating anionic guests
2) Su, Cheng-Yong; Cai, Yue-Peng; Chen, Chun-Long; Kang, Bei-Sheng; Inorg. Chem. 2001, 40(10), 2210-2211, DOI: 10.1021/ic0014282 ; Unusual Noninterpenetrating (3,6) Topological Network Assembled by Semirigid Benzimidazole-Based Bridging Ligand
3) Su, Cheng-Yong; Cai, Yue-Peng; Chen, Chun-Long; Smith, Mark D.; Kaim, Wolfgang; Zur Loye, Hans-Conrad; Journal of the American Chemical Society 2003, 125(28), 8595-8613, DOI: 10.1021/ja034267k ; Ligand-Directed Molecular Architectures: Self-Assembly of Two-Dimensional Rectangular Metallacycles and Three-Dimensional Trigonal or Tetragonal Prisms
4) Zhang, Qian; Zhang, Jianyong; Yu, Qiong-Yan; Pan, Mei; Su, Cheng-Yong; Cryst. Growth & Des. 2010, 10(9), 4076-4084, DOI: 10.1021/cg100742c ; Ring-Opening Isomerization Based on the 3-Connecting Node: Formation of a 0-D M2L3 Cage, 1-D Loop-and-Chain, and 2-D (6, 3) Network
5) Liu, Qing-Xiang; Hu, Ze-Liang; Yu, Shao-Cong; Zhao, Zhi-Xiang; Wei, Deng-Che; Li, Hui-Long; ACS Omega 2018, 3(4), 4035-4047, DOI: 10.1021/acsomega.8b00205 ; NHC Pd(II) and Ag(I) Complexes: Synthesis, Structure, and Catalytic Activity in Three Types of C-C Coupling Reactions