1,1'-((2,3,5,6-tetramethyl-1,4-phenylene)bis(methylene))bis(1H-imidazole)
CAS:1012075-54-5
分子式:C18H22N4
分子量:294.39408
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产品名称：1,4-Bis(imidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene
其他名称：bimx ; BTIB ; p-tmbix ; p-bitmb;1,1'-[(2,3,5,6-Tetramethyl-1,4-phenylene)bis(methylene)]bis[1H-imidazole]
CAS：1012075-54-5
3) Kose Yaman, Pelin; Arici, Mursel; Erer, Hakan; Yesilel, Okan Zafer; J. Mole. Struct. 2021, 1229, 129499, DOI: 10.1016/j.molstruc.2020.129499 ; The Effect of Metal Salts on The Structures of 2,2-Dimethylglutarate Complexes with a Flexible 1,4-bis(imidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene
4) Zhang, Yan; Luo, Wenping; Liu, Dongju; Xu, Yan; Li, Shun-Li; Li, Jingfu; Wu, Yong; Zhou, Yaoming; Fang, Min; Liu, Hong-Ke; Inorg. Chimi. Acta 2014, 409(PB), 512-517, DOI: 10.1016/j.ica.2013.09.043 ; Structures and photoluminescence properties of two cadmium(II) coordination polymers synthesized by flexible and rigid ligands
其他名称：bimx ; BTIB ; p-tmbix ; p-bitmb;1,1'-[(2,3,5,6-Tetramethyl-1,4-phenylene)bis(methylene)]bis[1H-imidazole]
CAS：1012075-54-5
结构信息
| 分子式 | C18H22N4 | 分子量 | 294.39408 | ||
| 性状照片 | |||||
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Zn(bdc)(bimx)] [r1]; [Cu(CO3)(btib)] [r2]; [Cd(BDC)(m-bitmb)(H2O)] [r4]
表征图谱
参考文献
1) Schaate, Andreas; Klingelhoefer, Stefan; Behrens, Peter; Wiebcke, Michael; Cryst. Growth & Des. 2008, 8(9), 3200-3205, DOI: 10.1021/cg701041k ; Two Zinc(II) Coordination Polymers Constructed with Rigid 1,4-Benzenedicarboxylate and Flexible 1,4-Bis(imidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene Linkers: From Interpenetrating Layers to Templated 3D Frameworks
2) Inoue, Tatsunari; Yamanishi, Katsunori; Kondo, Mitsuru; Inorg. Chem. 2013, 52(9), 4765-4767,DOI: 10.1021/ic400315g ; Solvent-Soluble Coordination Polymer That Reconstructs Cyclic Frameworks That Trap a Kinetically Labile [Cu(CO3)2]2- Unit相关产品
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