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1,1'-((2,3,5,6-tetramethyl-1,4-phenylene)bis(methylene))bis(1H-imidazole)
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1,1'-((2,3,5,6-tetramethyl-1,4-phenylene)bis(methylene))bis(1H-imidazole)
CAS:1012075-54-5 分子式:C18H22N4 分子量:294.39408
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产品名称:1,​4-​Bis(imidazol-​1-​ylmethyl)​-​2,​3,​5,​6-​tetramethylbenzene
其他名称:bimx ; BTIB ; p-​tmbix ; p-​bitmb;1,​1'-​[(2,​3,​5,​6-​Tetramethyl-​1,​4-​phenylene)​bis(methylene)​]​bis[1H-​imidazole]
CAS:1012075-54-5
结构信息
分子式 C18H22N4 分子量 294.39408
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Zn(bdc)​(bimx)​] [r1]; [Cu(CO3)(btib)] [r2]; [Cd(BDC)​(m-​bitmb)​(H2O)​] [r4]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Schaate, Andreas; Klingelhoefer, Stefan; Behrens, Peter; Wiebcke, Michael; Cryst. Growth & Des. 2008, 8(9), 3200-3205, DOI: 10.1021/cg701041k ; Two Zinc(II) Coordination Polymers Constructed with Rigid 1,​4-​Benzenedicarboxylate and Flexible 1,​4-​Bis(imidazol-​1-​ylmethyl)​-​2,​3,​5,​6-​tetramethylbenzene Linkers: From Interpenetrating Layers to Templated 3D Frameworks
2) Inoue, Tatsunari; Yamanishi, Katsunori; Kondo, Mitsuru; Inorg. Chem. 2013, 52(9), 4765-4767,DOI: 10.1021/ic400315g ; Solvent-​Soluble Coordination Polymer That Reconstructs Cyclic Frameworks That Trap a Kinetically Labile [Cu(CO3)​2]​2- Unit
3) Kose Yaman, Pelin; Arici, Mursel; Erer, Hakan; Yesilel, Okan Zafer; J. Mole. Struct. 2021, 1229, 129499, DOI: 10.1016/j.molstruc.2020.129499 ; The Effect of Metal Salts on The Structures of 2,​2-​Dimethylglutarate Complexes with a Flexible 1,​4-​bis(imidazol-​1-​ylmethyl)​-​2,​3,​5,​6-​tetramethylbenzene
4) Zhang, Yan; Luo, Wenping; Liu, Dongju; Xu, Yan; Li, Shun-Li; Li, Jingfu; Wu, Yong; Zhou, Yaoming; Fang, Min; Liu, Hong-Ke; Inorg. Chimi. Acta 2014, 409(PB), 512-517, DOI: 10.1016/j.ica.2013.09.043 ; Structures and photoluminescence properties of two cadmium(II) coordination polymers synthesized by flexible and rigid ligands

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1,1'-((2,3,5,6-tetramethyl-1,4-phenylene)bis(methylene))bis(1H-imidazole)
1,1'-((2,3,5,6-tetramethyl-1,4-phenylene)bis(methylene))bis(1H-imidazole)