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[1,1':4',1''-Terphenyl]-4,4''-dicarboxylic acid, 2',3',5',6'-tetramethyl-
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[1,1':4',1''-Terphenyl]-4,4''-dicarboxylic acid, 2',3',5',6'-tetramethyl-
[1,1':4',1''-Terphenyl]-4,4''-dicarboxylic acid, 2',3',5',6'-tetramethyl-
CAS:1394899-62-7 分子式:C24H22O4 分子量:374.42908
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产品名称:[1,1':4',1''-Terphenyl]-4,4''-dicarboxylic acid, 2',3',5',6'-tetramethyl-
其他名称:TPDC-4CH3 ; H2TTTP;2',​3',​5',​6'-​Tetramethyl[1,​1':4',​1''-​terphenyl]​-​4,​4''-​dicarboxylic acid
CAS:1394899-62-7
结构信息
分子式 C24H22O4 分子量 374.42908
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:UIO-68-4Me / PCN-57 (Zr, Hf) [r1,r3] ; PCN-72 [r2];
表征图谱
HNMR
MS
FTIR
NA
HPLC
NA
参考文献
1) Jiang, Hai-Long; Feng, Dawei; Liu, Tian-Fu; Li, Jian-Rong; Zhou, Hong-Cai; J. Am. Chem. Soc. 2012, 134(36), 14690-14693, DOI: 10.1021/ja3063919 ; Pore Surface Engineering with Controlled Loadings of Functional Groups via Click Chemistry in Highly Stable Metal-​Organic Frameworks
2) Liu, Yangyang; Chen, Ying-Pin; Liu, Tian-Fu; Yakovenko, Andrey A.; Raiff, Aaron M.; Zhou, Hong-Cai; CrystEngComm 2013, 15(45), 9688-9693, CrystEngComm, 2013,15, 9688-9693, Selective gas adsorption and unique phase transition properties in a stable magnesium metal-organic framework constructed from infinite metal chains
3) Klet, Rachel C.; Liu, Yangyang; Wang, Timothy C.; Hupp, Joseph T.; Farha, Omar K.; J. Mater. Chem. C 2016, 4(4), 1479-1485, DOI: 10.1039/C5TA07687K ; Evaluation of Bronsted acidity and proton topology in Zr- and Hf-​based metal-​organic frameworks using potentiometric acid-​base titration
4) Pang, Jiandong; Yuan, Shuai; Qin, Junsheng; Wu, Mingyan; Lollar, Christina T.; Li, Jialuo; Huang, Ning; Li, Bao; Zhang, Peng; Zhou, Hong-Cai; J. Am. Chem. Soc. 2018, 140(39), 12328-12332, DOI: 10.1021/jacs.8b07411 ; Enhancing Pore-​Environment Complexity Using a Trapezoidal Linker: Toward Stepwise Assembly of Multivariate Quinary Metal-​Organic Frameworks

5) Dascalu, Ioan-Andrei; Shova, Sergiu; Dumitrescu, Dan Gheorghe; Roman, Gheorghe; Bratanovici, Bogdan-Ionel; Ardeleanu, Rodinel; Lozan, Vasile; Polyhedron 2019, 170, 463-470, DOI: 10.1016/j.poly.2019.05.066 ; Coordination polymers of Cu(II)​, Co(II) and Cd(II) based on a tetramethyl-​substituted terphenyldicarboxylic acid

1394899-62-7-CS017249-MS.pdf 下载
1394899-62-7-CS017249.pdf 下载

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[1,1':4',1''-Terphenyl]-4,4''-dicarboxylic acid, 2',3',5',6'-tetramethyl-
[1,1':4',1''-Terphenyl]-4,4''-dicarboxylic acid, 2',3',5',6'-tetramethyl-