B,B',B'',B'''-(21H,23H-porphine-5,10,15,20-tetrayltetra-4,1-phenylene)tetrakis-Boronic acid
Boronic acid, B,B',B'',B'''-(21H,23H-porphine-5,10,15,20-tetrayltetra-4,1-phenylene)tetrakis-
CAS:97654-08-5
分子式:C44H34B4N4O8
分子量:790.00676
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品牌 / 纯度 / 包装
产品名称：5,10,15,20-Tetrakis(4-boronylphenyl)porphyrin
其他名称：H2TBPP; TDHB;Boronic acid, B,B',B'',B'''-(21H,23H-porphine-5,10,15,20-tetrayltetra-4,1-phenylene)tetrakis-
CAS：97654-08-5
其他名称：H2TBPP; TDHB;Boronic acid, B,B',B'',B'''-(21H,23H-porphine-5,10,15,20-tetrayltetra-4,1-phenylene)tetrakis-
CAS：97654-08-5
结构信息
| 分子式 | C44H34B4N4O8 | 分子量 | 790.00676 | ||
| 性状照片 |  |
||||
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料：COF-66 [r1]; MP-COF M=H, Zn, Cu [r2,r3]
表征图谱
参考文献
1) Wan, S.; Gandara, F.; Asano, A.; Furukawa, H.; Saeki, A.; Dey, S.; Liao, L.; Ambrogio, M.; Botros, Y.; Duan, X.; Seki, S.; Stoddart, J.; Yaghi, O. Chem. Mater., 2011, 23, 4094– 4097, DOI:10.1021/cm201140r ; Covalent Organic Frameworks with High Charge Carrier Mobility
2) Feng, X.; Chen, L.; Dong, Y.; Jiang, D.; Chem. Commun., 2011,47, 1979-1981, DOI: 10.1039/C0CC04386A ; Porphyrin-based two-dimensional covalent organic frameworks: synchronized synthetic control of macroscopic structures and pore parameters
3) Feng, X.; Liu, L.; Honsho, Y.; Saeki, A.; Seki, S.; Irle, S.; Dong, Y.; Nagai, A.; Jiang, D.; Angew. Chem., Int. Ed. 2012, 51(11), 2618-2622, DOI: 10.1002/ange.201106203 ; High‐Rate Charge‐Carrier Transport in Porphyrin Covalent Organic Frameworks: Switching from Hole to Electron to Ambipolar Conduction
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