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四(4-羧基-1,1'-联苯基)卟啉
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四(4-羧基-1,1'-联苯基)卟啉
4',​4''',​4''''',​4'''''''-​(21H,​23H-​porphine-​5,​10,​15,​20-​tetrayl)​tetrakis-[1,​1'-​Biphenyl]​-​4-​carboxylic acid
CAS:609365-68-6 分子式:C72H46N4O8 分子量:1095.15764
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产品名称:4',​4''',​4''''',​4'''''''-​(21H,​23H-​porphine-​5,​10,​15,​20-​tetrayl)​tetrakis-[1,​1'-​Biphenyl]​-​4-​carboxylic acid
其他名称:Por-PP; H2TBPP
CAS:609365-68-6
结构信息
分子式  C72H46N4O8 分子量  1095.15764
性状照片
性质说明
1) 609365-68-6难溶于常见溶剂
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料,如:CPM-99 [r2]; NU-1102 [r3]; FJI-H6/H7(Cu) [r4]
表征图谱
HNMR
NA 
MS
FTIR
NA
HPLC
NA
参考文献
1) Aya, Toshihiro; Hamilton, Andrew D. Bioorg. & Med. Chem. Lett. 2003, 13(16), 2651-2654  DOI:10.1016/S0960-894X(03)00551-1 ;Tetrabiphenylporphyrin-based receptors for protein surfaces show sub-nanomolar affinity and enhance unfolding 
2) Q. Lin , X. Bu , A. Kong , C. Mao , X. Zhao , F. Bu and P. Feng , J. Am. Chem. Soc., 2015, 137 , 2235-2238, DOI:10.1021/jacs.5b00076 ; New Heterometallic Zirconium Metalloporphyrin Frameworks and Their Heteroatom-Activated High-Surface-Area Carbon Derivatives
3) T. C. Wang , W. Bury , D. A. Gómez-Gualdrón , N. A. Vermeulen , J. E. Mondloch , P. Deria , K. Zhang , P. Z. Moghadam , A. A. Sarjeant , R. Q. Snurr , J. F. Stoddart , J. T. Hupp and O. K. Farha , J. Am. Chem. Soc., 2015, 137 , 3585-3591, DOI: 10.1021/ja512973b ; Ultrahigh Surface Area Zirconium MOFs and Insights into the Applicability of the BET Theory
4) J. Zheng,  M. Wu, F. Jiang,  W. Su, M. Hong, Chem. Sci., 2015,6, 3466-3470, DOI: 10.1039/C5SC00213C ; Stable porphyrin Zr and Hf metal–organic frameworks featuring 2.5 nm cages: high surface areas, SCSC transformations and catalyses
609365-68-6-CS016382-MS.pdf 下载
609365-68-6-CS017617-NEG.pdf 下载

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四(4-羧基-1,1'-联苯基)卟啉
四(4-羧基-1,1'-联苯基)卟啉