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[1,1':4',1'':3'',1''':4''',1''''-quinquephenyl]-4,4''''-dicarbonitrile, 5''-(4'-cyano[1,1'-biphenyl]-4-yl)
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[1,1':4',1'':3'',1''':4''',1''''-quinquephenyl]-4,4''''-dicarbonitrile, 5''-(4'-cyano[1,1'-biphenyl]-4-yl)
5''-(4'-cyano[1,1'-biphenyl]-4-yl)-[1,1':4',1'':3'',1''':4''',1''''-quinquephenyl]-4,4''''-dicarbonitrile
CAS:685114-67-4 分子式:C45H27N3 分子量:609.71598
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产品名称:1,​3,​5-​tri(4-​cyano-​4,​4-​biphenyl)​benzene
其他名称:TCB; CN-TBB;1,3,5-Tris(4‘-cyanobiphenyl-4-yl)benzene; 1,3,5-tris(4′-biphenyl-4″-carbonitrile)benzene
CAS:685114-67-4
结构信息
分子式 C45H27N3 分子量 609.71598
性状照片  
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料:
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Lu, J.; Tao, Y.; D'iorio, M.; Li, Y.; Ding, J.; Day, M.; Macromolecules 2004, 37(7), 2442-2449, DOI: 10.1021/ma030535n ; Pure Deep Blue Light-Emitting Diodes from Alternating Fluorene/Carbazole Copolymers by Using Suitable Hole-Blocking Materials 
2) Sirtl, T.; Schloegl, S.; Rastgoo-Lahrood, A.; Jelic, J.; Neogi, S.; Schmittel, M.; Heckl, W.; Reuter, K.; Lackinger, M.; J. Am. Chem. Soc. 2013, 135(2), 691-695, DOI: 10.1021/ja306834a ; Control of Intermolecular Bonds by Deposition Rates at Room Temperature: Hydrogen Bonds versus Metal Coordination in Trinitrile Monolayers 
3) Gaberle, J.; Gao, D.; Watkins, M.; Shluger, A.; J. Phys. Chem. C 2016, 120(7), 3913-3921, DOI: 10.1021/acs.jpcc.5b12028
4) Gaberle, J.; Gao, D.; Shluger, A.; Amrous, A.; Bocquet, F.; Nony, L.; Para, F.; Loppacher, C.; Lamare, S.; Cherioux, F.; J. Phys. Chem. C 2017, 121(8), 4393-4403, DOI: 10.1021/acs.jpcc.6b12738

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[1,1':4',1'':3'',1''':4''',1''''-quinquephenyl]-4,4''''-dicarbonitrile, 5''-(4'-cyano[1,1'-biphenyl]-4-yl)
[1,1':4',1'':3'',1''':4''',1''''-quinquephenyl]-4,4''''-dicarbonitrile, 5''-(4'-cyano[1,1'-biphenyl]-4-yl)