![[1,1':4',1'':3'',1''':4''',1''''-quinquephenyl]-4,4''''-dicarbonitrile, 5''-(4'-cyano[1,1'-biphenyl]-4-yl)](http://www.chemsoon.com.cn//upload/0201/93e1d2dc621c1b84e44f1c2bb3568617.png)
[1,1':4',1'':3'',1''':4''',1''''-quinquephenyl]-4,4''''-dicarbonitrile, 5''-(4'-cyano[1,1'-biphenyl]-4-yl)
5''-(4'-cyano[1,1'-biphenyl]-4-yl)-[1,1':4',1'':3'',1''':4''',1''''-quinquephenyl]-4,4''''-dicarbonitrile
CAS:685114-67-4
分子式:C45H27N3
分子量:609.71598
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品牌 / 纯度 / 包装
产品名称：1,3,5-tri(4-cyano-4,4-biphenyl)benzene
其他名称：TCB; CN-TBB;1,3,5-Tris(4‘-cyanobiphenyl-4-yl)benzene; 1,3,5-tris(4′-biphenyl-4″-carbonitrile)benzene
CAS：685114-67-4
其他名称：TCB; CN-TBB;1,3,5-Tris(4‘-cyanobiphenyl-4-yl)benzene; 1,3,5-tris(4′-biphenyl-4″-carbonitrile)benzene
CAS：685114-67-4
结构信息
| 分子式 | C45H27N3 | 分子量 | 609.71598 | ||
| 性状照片 | |||||
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料：
表征图谱
参考文献
1) Lu, J.; Tao, Y.; D'iorio, M.; Li, Y.; Ding, J.; Day, M.; Macromolecules 2004, 37(7), 2442-2449, DOI: 10.1021/ma030535n ; Pure Deep Blue Light-Emitting Diodes from Alternating Fluorene/Carbazole Copolymers by Using Suitable Hole-Blocking Materials
2) Sirtl, T.; Schloegl, S.; Rastgoo-Lahrood, A.; Jelic, J.; Neogi, S.; Schmittel, M.; Heckl, W.; Reuter, K.; Lackinger, M.; J. Am. Chem. Soc. 2013, 135(2), 691-695, DOI: 10.1021/ja306834a ; Control of Intermolecular Bonds by Deposition Rates at Room Temperature: Hydrogen Bonds versus Metal Coordination in Trinitrile Monolayers
3) Gaberle, J.; Gao, D.; Watkins, M.; Shluger, A.; J. Phys. Chem. C 2016, 120(7), 3913-3921, DOI: 10.1021/acs.jpcc.5b12028
4) Gaberle, J.; Gao, D.; Shluger, A.; Amrous, A.; Bocquet, F.; Nony, L.; Para, F.; Loppacher, C.; Lamare, S.; Cherioux, F.; J. Phys. Chem. C 2017, 121(8), 4393-4403, DOI: 10.1021/acs.jpcc.6b12738
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