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Phosphonic acid, P,P'-[5'-(4-phosphonophenyl)[1,1':3',1''-terphenyl]-4,4''-diyl]bis-
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Phosphonic acid, P,P'-[5'-(4-phosphonophenyl)[1,1':3',1''-terphenyl]-4,4''-diyl]bis-
Phosphonic acid, P,P'-[5'-(4-phosphonophenyl)[1,1':3',1''-terphenyl]-4,4''-diyl]bis-
CAS:1045720-71-5 分子式:C24H21O9P3 分子量:546.33954
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产品名称:1,​3,​5-​Benzene-​tri-​p-​phenylphosphonic acid
其他名称:H6PPB;P,​P'-​[5'-​(4-​Phosphonophenyl)​[1,​1':3',​1''-​terphenyl]​-​4,​4''-​diyl]​bis[phosphonic acid]
CAS:1045720-71-5
结构信息
分子式 C24H21O9P3 分子量 546.33954
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:CALF-​28 [r3]; MFM-500(M) (M = Ni, Co) [r4]; CAU-25 / [Zn2(H2PPB)(H2O)2] [r5]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Beckmann, Jens; Ruettinger, Roman; Schwich, Torsten; Cryst. Growth & Des. 2008, 8(9), 3271-3276, DOI: 10.1021/cg8000569 ; 1,​3,​5-​Benzene-​tri-​p-​phenylphosphonic acid. A new building block in supramolecular chemistry
2) Ouellette, Wayne; Wang, Guangbin; Liu, Hongxue; Yee, Gordon T.; O'Connor, Charles J.; Zubieta, Jon; Inorg. Chem. 2009, 48(3), 953-963, DOI: 10.1021/ic801450m ; The Hydrothermal and Structural Chemistry of Oxovanadium-​Arylphosphonate Networks and Frameworks
3) Mah, Roger K.; Lui, Melanie W.; Shimizu, George K. H.; Inorg. Chem. 2013, 52(13), 7311-7313, DOI: 10.1021/ic400274e ; Enhancing Order and Porosity in a Highly Robust Tin(IV) Triphosphonate Framework
4) Pili, Simona; Argent, Stephen P.; Morris, Christopher G.; Rought, Peter; Garcia-Sakai, Victoria; Silverwood, Ian P.; Easun, Timothy L.; Li, Ming; Warren, Mark R.; Murray, Claire A.; Tang, Chiu C.; Yang, Sihai; Schroder, Martin; J. Am. Chem. Soc. 2016, 138(20), 6352-6355, DOI: 10.1021/jacs.6b02194 ; Proton Conduction in a Phosphonate-​Based Metal-​Organic Framework Mediated by Intrinsic "Free Diffusion inside a Sphere"

5) Hermer, N.; Reinsch, H.; Mayer, P.; Stock, N.; CrystEngComm 2016, 18(42), 8147-8150, DOI: 10.1039/C6CE01580H ; Synthesis and characterisation of the porous zinc phosphonate [Zn2(H2PPB)​(H2O)​2]​·xH2O

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Phosphonic acid, P,P'-[5'-(4-phosphonophenyl)[1,1':3',1''-terphenyl]-4,4''-diyl]bis-
Phosphonic acid, P,P'-[5'-(4-phosphonophenyl)[1,1':3',1''-terphenyl]-4,4''-diyl]bis-