1H-Benzimidazole-2-methanamine, N,N-bis(1H-benzimidazol-2-ylmethyl)-
Tris((1H-benzo[d]imidazol-2-yl)methyl)amine
CAS:64019-57-4
分子式:C24H21N7
分子量:407.47044
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产品名称：Tris(benzimidazolylmethyl)amine
其他名称：(BimH)3 ; TBIA ; 3-TPyMNTB;1-(1H-Benzimidazol-2-yl)-N,N-bis(1H-benzimidazol-2-ylmethyl)methanamine; N,N,N-Tris(1H-benzimidazol-2-ylmethyl)amine; N,N,N-Tris(2-benzimidazolylmethyl)amine; TCMDC 124132; Tris(1H-benzimidazol-2-ylmethyl)amine; Tris(2-benzimidazolylmethyl)amine; Tris(2-benzimidazoylmethyl)amine; Tris(benzimidazole-2-yl-methyl)amine;
CAS：64019-57-4
3) Tang, Yongming; Zhang, Fan; Hu, Shengxiang; Cao, Ziyi; Wu, Zhenglei; Jing, Wenheng; Corrosion Science 2013, 74, 271-282, DOI: 10.1016/j.corsci.2013.04.053 ; Novel benzimidazole derivatives as corrosion inhibitors of mild steel in the acidic media. Part I: Gravimetric, electrochemical, SEM and XPS studies
4) Zhang, Shu-Ran; Du, Dong-Ying; Qin, Jun-Sheng; Bao, Shao-Juan; Li, Shun-Li; He, Wen-Wen; Lan, Ya-Qian; Shen, Ping; Su, Zhong-Min; Chem.- Eur. J. 2014, 20(13), 3589-3594, DOI: 10.1002/chem.201304692 ; A Fluorescent Sensor for Highly Selective Detection of Nitroaromatic Explosives Based on a 2D, Extremely Stable, Metal-Organic Framework
其他名称：(BimH)3 ; TBIA ; 3-TPyMNTB;1-(1H-Benzimidazol-2-yl)-N,N-bis(1H-benzimidazol-2-ylmethyl)methanamine; N,N,N-Tris(1H-benzimidazol-2-ylmethyl)amine; N,N,N-Tris(2-benzimidazolylmethyl)amine; TCMDC 124132; Tris(1H-benzimidazol-2-ylmethyl)amine; Tris(2-benzimidazolylmethyl)amine; Tris(2-benzimidazoylmethyl)amine; Tris(benzimidazole-2-yl-methyl)amine;
CAS：64019-57-4
结构信息
| 分子式 | C24H21N7 | 分子量 | 407.47044 | ||
| 性状照片 | |||||
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Eu(3-TPyMNTB)2] [r5]; π-MnBr-cages [r6];
2) 可作为Click反应的催化剂 [r2];
3) 可作为防锈剂:[r3]; [Eu(3-TPyMNTB)2] [r5]; π-MnBr-cages [r6]
表征图谱
参考文献
1) hompson, Laurence K.; Ramaswamy, Baratham S.; Seymour, Elizabeth A.; Canadian J. Chem. 1977, 55(5), 878-888, DOI: 10.1139/v77-122 ; Cobalt(II) and zinc(II) complexes of the 'tripod' ligand tris(2-benzimidazolylmethyl)amine. Some five-coordinate derivatives and some with mixed stereochemistries
2) Rodionov, Valentin O.; Presolski, Stanislav I.; Diaz Diaz, David; Fokin, Valery V.; Finn, M. G.; Journal of the American Chemical Society 2007, 129(42), 12705-12712, DOI: 10.1021/ja072679d ; Ligand-Accelerated Cu-Catalyzed Azide-Alkyne Cycloaddition: A Mechanistic Report5) iu, Yu; Pan, Mei; Yang, Qing-Yuan; Fu, Lei; Li, Kang; Wei, Shi-Chao; Su, Cheng-Yong; Chem. Mater. 2012, 24(10), 1954-1960, DOI: 10.1021/cm3008254 ; Dual-Emission from a Single-Phase Eu-Ag Metal-Organic Framework: An Alternative Way to Get White-Light Phosphor6) Li, Guo-Ling; Zhuo, Zhu; Wang, Bin; Cao, Xue-Li; Su, Hai-Feng; Wang, Wei; Huang, You-Gui; Hong, Maochun; Journal of the American Chemical Society 2021, 143(29), 10920-10929, DOI: 10.1021/jacs.1c01161 ; Constructing π-Stacked Supramolecular Cage Based Hierarchical Self-Assemblies via π···π Stacking and Hydrogen Bonding
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