产品名称:1,1',1''-(1,3,5-Benzenetriyl)tris[1H-benzimidazole]其他名称:TBIB CAS:1207945-97-8
结构信息
分子式 |
C27H18N6 |
分子量 |
426.47202 |
性状照片 |
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性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料: [Cd3(TBIB)4(BTC)2] [r2]; [Zn2(TBIB)2(HTCPB)2] [r4]; [Zn3(TBIB)2(Cl)6] [r5]
2) 可作为OLED前驱体使用
表征图谱
参考文献
1) White, Wade; Hudson, Zachary M.; Feng, Xiaodong; Han, Sijin; Lu, Zheng-Hong; Wang, Suning; Dalton Trans. 2010, 39(3), 892-899, DOI: 10.1039/B918203A ; Linear and star-shaped benzimidazolyl derivatives: syntheses, photophysical properties and use as highly efficient electron transport materials in OLEDs
2) Agarwal, Rashmi A.; Polyhedron 2015, 85, 740-747, DOI: 10.1016/j.poly.2014.09.041 ; Structural diversity and luminescence properties of the novel {[Cd3(TBIB)4(BTC)2]·2C2H5OH·11H2O}n and {[Zn(TBIB)(HBTC)]·3H2O}n coordination polymers
3) Lai, Cheng-Chang; Huang, Min-Jie; Chou, Ho-Hsiu; Liao, Chuang-Yi; Rajamalli, Pachaiyappan; Cheng, Chien-Hong; Adv. Func. Mater. 2015, 25(34), 5548-5556, DOI: 10.1002/adfm.201502079 ; m-Indolocarbazole Derivative as a Universal Host Material for RGB and White Phosphorescent OLEDs
4) Agarwal, Rashmi A.; Gupta, Anoop K.; De, Dinesh From Crystal Growth & Design 2019, 19(3), 2010-2018, DOI: 10.1021/acs.cgd.8b01462 ; Flexible Zn-MOF Exhibiting Selective CO2 Adsorption and Efficient Lewis Acidic Catalytic Activity
5) Agarwal, Rashmi A.; Das, Amit; Omar, Shobit; J. Phys. Chem. C 2020, 124(35), 18901-18910, DOI: 10.1021/acs.jpcc.0c05013 ; High 3D Proton Conductivity of a 2D Zn(II) Metal-Organic Framework Synthesized via Water-Assisted Single-Crystal-to-Single-Crystal Phase Transformation