CAS 62968-45-0|HTB|CHEMSOON

产品名称：benzene hexathiol
其他名称：HTB ; BHT
CAS：62968-45-0

结构信息

分子式	C₆H₆S₆		分子量	270.51
性状照片	白色至淡黄色固体

性质说明

1) 62968-45-0 微溶于DMF、DMSO等
2) 氮气保护，冷藏储存

合成应用

1) 可作为配体用于合成MOF材料：M-HTB 或 M3(BHT)2 M=Cu [r6]/ Ag [r7]/ Co [r5]/ Ni [r4]/ Fe

表征图谱

HNMR

FTIR

HPLC

参考文献

1) Richter, A.; Engels, V.; Beye, N.; Fanghaenel, E.; Zeitschrift fuer Chemie 1989, 29(12), 444-445

2) Harnisch, J. A.; Angelici, R. J.; Inorg. Chim. Acta. 2000, 300-302, 273-279, DOI: 10.1016/S0020-1693(99)00552-6 ; Gold and platinum benzenehexathiolate complexes as large templates for the synthesis of 12-coordinate polyphosphine macrocycles

3) Turner, D.; Vaid, T.; Stephens, P.; Stone, K.; DiPasquale, A.; Rheingold, A.; J. Am. Chem. Soc. 2008, 130, 1, 14-15, DOI: 10.1021/ja0770983 ; Semiconducting Lead−Sulfur−Organic Network Solids

4) Kambe, T.; Sakamoto, R.; Hoshiko, K.; Takada, K.; Miyachi, M.; Ryu, J.-H.; Sasaki, S.; Kim, J.; Nakazato, K.; Takata, M.; Nishihara, H. J. Am. Chem. Soc. 2013, 135, 2462– 2465, DOI: 10.1021/ja312380b ; π-Conjugated Nickel Bis(dithiolene) Complex Nanosheet

5) Clough, A.; Yoo, J.; Mecklenburg, M.; Marinescu, S.; J. Am. Chem. Soc. 2015, 137, 1, 118-121, DOI: 10.1021/ja5116937 ; Two-Dimensional Metal–Organic Surfaces for Efficient Hydrogen Evolution from Water

6) Huang, X., Sheng, P., Tu, Z. et al.Nat. Commun. 2015, 6, 7408, DOI: 10.1038/ncomms8408 ; A two-dimensional π–d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour

7) Huang, X.; Li, H. S.; Tu, Z. Y.; Liu, L. Y.; Wu, X. Y.; Chen, J.; Liang, Y. Y.; Zou, Y.; Yi, Y. P.; Sun, J. L.; Xu, W.; Zhu, D. B.; J. Am. Chem. Soc. 2018, 140 (45), 15153– 15156, DOI: 10.1021/jacs.8b07921 ; Highly Conducting Neutral Coordination Polymer with Infinite Two-Dimensional Silver–Sulfur Networks

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