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2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane
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2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane
2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane
CAS:29261-33-4 分子式:C12F4N4 分子量:276.15
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产品名称:Tetrafluorotetracyan​o-​p-​quinodimethane;
其他名称:F4-​TCNQ ; TCNQF4 ; Perfluoro-​TCNQ;2,​2'-​(2,​3,​5,​6-​Tetrafluoro-​2,​5-​cyclohexadiene-​1,​4-​diylidene)​bis[propanedinitrile​]​; 2,​3,​5,​6-​Tetrafluoro-​7,​7,​8,​8-​tetracyano-​p-​quinodimethane; 2,​3,​5,​6-​Tetrafluoro-​7,​7,​8,​8-​tetracyanoquinodimet​hane; 2-​[4-​(Dicyanomethylidene)​-​2,​3,​5,​6-​tetrafluorocyclohexa​-​2,​5-​dien-​1-​ylidene]​propanedinitrile; 7,​7,​8,​8-​Tetracyano-​2,​3,​5,​6-​tetrafluoroquinodime​thane; F4-​TCNQ; Perfluoro-​7,​7,​8,​8-​tetracyano-​p-​quinodimethane; Perfluoro-​TCNQ; Perfluorotetracyano-​p-​quinodimethane; TCNQF4; Tetrafluoro-​TCNQ;
CAS:29261-33-4
结构信息
分子式 C12N4F4 分子量 276.1488
性状照片  
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料:
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Wheland, R. C.; Martin, E. L.; J. Org. Chem. 1975, 40(21), 3101-3109, DOI: 10.1021/jo00909a019 ; Synthesis of substituted 7,​7,​8,​8-​tetracyanoquinodimethanes
2) Mouri, Shinichiro; Miyauchi, Yuhei; Matsuda, Kazunari; Nano Lett. 2013, 13(12), 5944-5948, DOI: 10.1021/nl403036h ; Tunable Photoluminescence of Monolayer MoS2 via Chemical Doping
3) Chen, Wei; Chen, Shi; Qi, Dong Chen; Gao, Xing Yu; Wee, Andrew Thye Shen; Journal of the American Chemical Society 2007, 129(34), 10418-10422, DOI: 10.1021/ja071658g ; Surface Transfer p-​Type Doping of Epitaxial Graphene
4) Wang, Qi; Dong, Qingfeng; Li, Tao; Gruverman, Alexei; Huang, Jinsong; Adv. Mater. 2016, 28(31), 6734-6739, DOI: 10.1002/adma.201600969 ; Thin Insulating Tunneling Contacts for Efficient and Water-​Resistant Perovskite Solar Cells

5) He, Gufeng; Pfeiffer, Martin; Leo, Karl; Hofmann, Michael; Birnstock, Jan; Pudzich, Robert; Salbeck, Josef; Appl. Phys. Lett. 2004, 85(17), 3911-3913, DOI: 10.1063/1.1812378 ; High-​efficiency and low-​voltage p-​i-​n electrophosphorescent organic light-​emitting diodes with double-​emission layers6) Takenobu, Taishi; Takano, Takumi; Shiraishi, Masashi; Murakami, Yousuke; Ata, Masafumi; Kataura, Hiromichi; Achiba, Yohji; Iwasa, Yoshihiro; Nature Mater. 2003, 2(10), 683-688, DOI: 10.1038/nmat976 ; Stable and controlled amphoteric doping by encapsulation of organic molecules inside carbon nanotubes7) Blochwitz, J.; Pfeiffer, M.; Fritz, T.; Leo, K.; Appl. Phys. Lett. 1998, 73(6), 729-731, DOI: 10.1063/1.121982 ; Low voltage organic light emitting diodes featuring doped phthalocyanine as hole transport material

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2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane
2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane