产品名称:1,1'-bis(4-carboxyphenyl)-(4,4'-bipyridinium) dichloride)其他名称:H2bcbp·2Cl ; H2bcbpCl2;4,4'-Bipyridinium, 1,1'-bis(4-carboxyphenyl)-, dichloride CAS:60095-59-2
结构信息
分子式 |
C24N2O4+2.2[Cl-] |
分子量 |
451.1738 |
性状照片 |
|
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Eu3(bcbp)3(NO3)7(OH)2]n [r2]; [Cd(bpybdc)(NO3)2]·H2O [r3]
表征图谱
参考文献
1) Gutov, A. V.; Rusanov, E. B.; Ryabitskii, A. B.; Tsimbal, I. F.; Chernega, A. N.; Russ. J. General Chem. 2009, 79(9), 1910-1918, DOI: 10.1134/S1070363209090175 ; Crystalline and molecular design of functionalized viologens
2) Liu, Jian-Jun; Guan, Ying-Fang; Lin, Mei-Jin; Huang, Chang-Cang; Dai, Wen-Xin; Cryst. Growth & Des. 2015, 15(10), 5040-5046, DOI: 10.1021/acs.cgd.5b01026 ; Luminescent Coordination Polymer with Conjugated Lewis Acid Sites for the Detection of Organic Amines
3) Liu, Jian-Jun; Guan, Ying-Fang; Lin, Mei-Jin; Huang, Chang-Cang; Dai, Wen-Xin; Cryst. Growth & Des. 2016, 16(5), 2836-2842, DOI: 10.1021/acs.cgd.6b00163 ; Anion-Mediated Architecture and Photochromism of Rigid Bipyridinium-Based Coordination Polymers
4) Sui, Qi; Yuan, Ye; Yang, Ning-Ning; Li, Xin; Gong, Teng; Gao, En-Qing; Wang, Lin; J. Mater. Chem. C 2017, 5(47), 12400-12408, DOI: 10.1039/C7TC04208F ; Coordination-modulated piezochromism in metal-viologen materials