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4,4'-Bipyridinium, 1,1'-bis(4-carboxyphenyl)-, chloride (1:2)
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4,4'-Bipyridinium, 1,1'-bis(4-carboxyphenyl)-, chloride (1:2)
4,4'-Bipyridinium, 1,1'-bis(4-carboxyphenyl)-, chloride (1:2)
CAS:60095-59-2 分子式:C24N2O4+2.2[Cl-] 分子量:451.1738
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产品名称:1,​1'-​bis(4-​carboxyphenyl)​-​(4,​4'-​bipyridinium) dichloride)​
其他名称:H2bcbp·2Cl ; H2bcbpCl2;4,​4'-​Bipyridinium, 1,​1'-​bis(4-​carboxyphenyl)​-​, dichloride
CAS:60095-59-2
结构信息
分子式 C24N2O4+2.2[Cl-] 分子量 451.1738
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Eu3(bcbp)​3(NO3)​7(OH)​2]​n [r2]; [Cd(bpybdc)​(NO3)​2]​·H2O [r3]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Gutov, A. V.; Rusanov, E. B.; Ryabitskii, A. B.; Tsimbal, I. F.; Chernega, A. N.; Russ. J. General Chem. 2009, 79(9), 1910-1918, DOI: 10.1134/S1070363209090175 ; Crystalline and molecular design of functionalized viologens
2) Liu, Jian-Jun; Guan, Ying-Fang; Lin, Mei-Jin; Huang, Chang-Cang; Dai, Wen-Xin; Cryst. Growth & Des. 2015, 15(10), 5040-5046, DOI: 10.1021/acs.cgd.5b01026 ; Luminescent Coordination Polymer with Conjugated Lewis Acid Sites for the Detection of Organic Amines
3) Liu, Jian-Jun; Guan, Ying-Fang; Lin, Mei-Jin; Huang, Chang-Cang; Dai, Wen-Xin; Cryst. Growth & Des. 2016, 16(5), 2836-2842, DOI: 10.1021/acs.cgd.6b00163 ; Anion-​Mediated Architecture and Photochromism of Rigid Bipyridinium-​Based Coordination Polymers
4) Sui, Qi; Yuan, Ye; Yang, Ning-Ning; Li, Xin; Gong, Teng; Gao, En-Qing; Wang, Lin; J. Mater. Chem. C 2017, 5(47), 12400-12408, DOI: 10.1039/C7TC04208F ; Coordination-​modulated piezochromism in metal-​viologen materials

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4,4'-Bipyridinium, 1,1'-bis(4-carboxyphenyl)-, chloride (1:2)
4,4'-Bipyridinium, 1,1'-bis(4-carboxyphenyl)-, chloride (1:2)