1,1’-双(2,4-二硝基苯基)-4,4’-二氯化联吡啶
1,1 -Bis(2,4-dinitrophenyl)-4,4 -bipyridinium Dichloride
CAS:41168-79-0
分子式:C22H16Cl2N6O8
分子量:563.303842544556
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产品名称：N,N'-Bis(2,4-dinitrophenyl)-4,4'-bipyridinium dichloride
其他名称：BDB;4,4'-Bipyridinium, 1,1'-bis(2,4-dinitrophenyl)-, dichloride; 1,1'-Bis(2,4-dinitrophenyl)-4,4'-bipyridinium dichloride;
CAS：41168-79-0
3) Sui, Qi; Ren, Xiang-Ting; Dai, Yu-Xiang; Wang, Kai; Li, Wen-Tao; Gong, Teng; Fang, Jia-Jia; Zou, Bo; Gao, En-Qing; Wang, Lin; Chem. Sci. 2017, 8(4), 2758-2768, DOI: 10.1039/C6SC04579K ; Piezochromism and hydrochromism through electron transfer: new stories for viologen materials
4) Liu, Jian-Jun; Guan, Ying-Fang; Lin, Mei-Jin; Huang, Chang-Cang; Dai, Wen-Xin; Cryst. Growth Des. 2015, 15(10), 5040-5046, DOI: 10.1021/acs.cgd.5b01026 ; Luminescent Coordination Polymer with Conjugated Lewis Acid Sites for the Detection of Organic Amines
其他名称：BDB;4,4'-Bipyridinium, 1,1'-bis(2,4-dinitrophenyl)-, dichloride; 1,1'-Bis(2,4-dinitrophenyl)-4,4'-bipyridinium dichloride;
CAS：41168-79-0
结构信息
| 分子式 | C22N6O8+2.2[Cl-] | 分子量 | 547.1768 | ||
| 性状照片 | |||||
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
2) 2-8℃密封保存
合成应用
1) 可与氨基单体反应合成COF材料：BDB-TAPB-COGF [r2];
2) 可作为前驱体用于超分子配体；
3) 可用于合成 viologen-based porous organic polymers [r5]
表征图谱
参考文献
1) Nanasawa, Masato; Miwa, Makio; Hirai, Michiko; Kuwabara, Tetsuo; J. Org. Chem. 2000, 65(2), 593-595,DOI: 10.1021/jo990911v ; Synthesis of viologens with extended π-conjugation and their photochromic behavior on near-IR absorption
2) Das, Gobinda; Skorjanc, Tina; Sharma, Sudhir Kumar; Gandara, Felipe; Lusi, Matteo; Shankar Rao, D. S.; Vimala, Sridurai; Krishna Prasad, Subbarao; Raya, Jesus; Han, Dong Suk; Jagannathan, Ramesh; Olsen, John-Carl; Trabolsi, Ali; Journal of the American Chemical Society 2017, 139(28), 9558-9565, DOI: 10.1021/jacs.7b02836 ; Viologen-Based Conjugated Covalent Organic Networks via Zincke Reaction5) Hua, Carol; Chan, Bun; Rawal, Aditya; Tuna, Floriana; Collison, David; Hook, James M.; D'Alessandro, Deanna M.; J. Mater. Chem. C 2016, 4(13), 2535-2544, DOI: 10.1039/C6TC00132G ; Redox tunable viologen-based porous organic polymers
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