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Benzoic acid, 4,4',4'',4'''-tricyclo[3.3.1.13,7]decane-1,3,5,7-tetrayltetrakis- (9CI)
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Benzoic acid, 4,4',4'',4'''-tricyclo[3.3.1.13,7]decane-1,3,5,7-tetrayltetrakis- (9CI)
Benzoic acid, 4,4',4'',4'''-tricyclo[3.3.1.13,7]decane-1,3,5,7-tetrayltetrakis- (9CI)
CAS:154694-31-2 分子式:C38H32O8 分子量:616.656
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产品名称:adamantanetetrabenzoic acid
其他名称:H4ATB;1,​3,​5,​7-​tetra(carboxyphenyl)​adamantane ; Benzoic acid, 4,​4',​4'',​4'''-​tricyclo[3.3.1.13,​7]​decane-​1,​3,​5,​7-​tetrayltetrakis-
CAS:154694-31-2
结构信息
分子式 C38H32O8 分子量 616.65588
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:MOF-​33 [r2] ; TCF-3 [r5] ; ZRTE-​10 [r6]
表征图谱
HNMR
MS
FTIR
NA
HPLC
NA
参考文献
1) Reichert, Veronica R.; Mathias, Lon J.; Macromolecules 1994, 27(24), 7015-7023, DOI: 10.1021/ma00102a002 ; Expanded Tetrahedral Molecules from 1,​3,​5,​7-​Tetraphenyladamantane
2) Kim, Jaheon; Chen, Banglin; Reineke, Theresa M.; Li, Hailian; Eddaoudi, Mohamed; Moler, David B.; O'Keeffe, Michael; Yaghi, Omar M.; Journal of the American Chemical Society 2001, 123(34), 8239-8247, DOI: 10.1021/ja010825o ; Assembly of Metal-​Organic Frameworks from Large Organic and Inorganic Secondary Building Units: New Examples and Simplifying Principles for Complex Structures
3) Zulfiqar, Sonia; Mantione, Daniele; El Tall, Omar; Sarwar, Muhammad Ilyas; Ruiperez, Fernando; Rothenberger, Alexander; Mecerreyes, David; Journal of Materials Chemistry A 2016, 4(21), 8190-8197, DOI: 10.1039/C6TA01457G ; Nanoporous amide networks based on tetraphenyladamantane for selective CO2 capture
4) Zhao, Tian; Heering, Christian; Boldog, Ishtvan; Domasevitch, Konstantin V.; Janiak, Christoph; CrystEngComm 2017, 19(5), 776-780, DOI: 10.1039/C6CE02384C ; A view on systematic truncation of tetrahedral ligands for coordination polymers
5) Bassanetti, Irene; Bracco, Silvia; Comotti, Angiolina; Negroni, Mattia; Bezuidenhout, Charl; Canossa, Stefano; Mazzeo, Paolo Pio; Marchio, Luciano; Sozzani, Piero; Journal of Materials Chemistry A: Materials for Energy and Sustainability 2018, 6(29), 14231-14239, DOI: 10.1039/C8TA02211A ; Flexible porous molecular materials responsive to CO2, CH4 and Xe stimuli
6) Nateghi, Bahareh; Domasevitch, Kostiantyn V.; Bulanek, Roman; Janiak, Christoph; Boldog, Ishtvan; Inorganic Chemistry 2019, 58(19), 12786-12797, DOI: 10.1021/acs.inorgchem.9b01721 ; Ligand Excess "Inverse-​Defected" Zr6 Tetrahedral Tetracarboxylate Framework and Its Thermal Transformation
154694-31-2-CS017699.pdf 下载
154694-31-2-CS017699-MS.pdf 下载
154694-31-2-CS017912.pdf 下载
154694-31-2-CS018057.pdf 下载

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Benzoic acid, 4,4',4'',4'''-tricyclo[3.3.1.13,7]decane-1,3,5,7-tetrayltetrakis- (9CI)
Benzoic acid, 4,4',4'',4'''-tricyclo[3.3.1.13,7]decane-1,3,5,7-tetrayltetrakis- (9CI)