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1,3,5,7-四(4-碘苯基)金刚烷
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1,3,5,7-四(4-碘苯基)金刚烷
Tricyclo[3.3.1.13,7]decane, 1,3,5,7-tetrakis(4-iodophenyl)-
CAS:144970-30-9 分子式:C34H28I4 分子量:944.204018592834
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产品名称:1,​3,​5,​7-​Tetrakis(4-​iodophenyl)​adamantane
其他名称:TIPA;1,​3,​5,​7-​Tetrakis(4-​iodophenyl)​tricyclo[3.3.1.13,​7]​decan ; 1,​3,​5,​7-​Tetrakis(p-​iodophenyl)​adamantane
CAS:144970-30-9
结构信息
分子式 C34H28I4 分子量 944.20212
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为中间体用于合成MOF材料配体或者COF材料单体:PAFad [r5]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Mathias, Lon J.; Reichert, Veronica R.; Muir, Andrew V. G.; Chem. Mater. 1993, 5(1), 4-5, DOI: 10.1021/cm00025a002 ; Synthesis of rigid tetrahedral tetrafunctional molecules from 1,​3,​5,​7-​tetrakis(4-​iodophenyl)​adamantane
2) Lu, Weigang; Yuan, Daqiang; Zhao, Dan; Schilling, Christine Inge; Plietzsch, Oliver; Muller, Thierry; Brase, Stefan; Guenther, Johannes; Blumel, Janet; Krishna, Rajamani; Li, Zhen; Zhou, Hong-Cai; Chem. Mater. 2010, 22(21), 5964-5972, DOI: 10.1021/cm1021068 ; Porous Polymer Networks: Synthesis, Porosity, and Applications in Gas Storage​/Separation
3) Wang, Shujun; Oldham, Warren J., Jr.; Hudack, Raymond A., Jr.; Bazan, Guillermo C.; Journal of the American Chemical Society 2000, 122(24), 5695-5709, DOI: 10.1021/ja992924w ; Synthesis, Morphology, and Optical Properties of Tetrahedral Oligo(phenylenevinylene) Materials
4) Xie, Lin-Hua; Suh, Myunghyun Paik; Chem. Eur. J. 2013, 19(35), 11590-11597, DOI: 10.1002/chem.201301822 ; High CO2-​Capture Ability of a Porous Organic Polymer Bifunctionalized with Carboxy and Triazole Groups
5) Verde-Sesto, Ester; Merino, Estibaliz; Rangel-Rangel, Elizabeth; Corma, Avelino; Iglesias, Marta; Sanchez, Felix; ACS Sustainable Chem. & Eng. 2016, 4(3), 1078-1084, DOI: 10.1021/acssuschemeng.5b01147 ; Postfunctionalized Porous Polymeric Aromatic Frameworks with an Organocatalyst and a Transition Metal Catalyst for Tandem Condensation-​Hydrogenation Reactions

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1,3,5,7-四(4-碘苯基)金刚烷
1,3,5,7-四(4-碘苯基)金刚烷