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2-Methyl-[1,1'-biphenyl]-4,4'-dicarboxylic acid
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2-Methyl-[1,1'-biphenyl]-4,4'-dicarboxylic acid
2-Methyl-[1,1'-biphenyl]-4,4'-dicarboxylic acid
CAS:1186048-28-1 分子式:C15H12O4 分子量:256.25338
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产品名称:2-​methyl-​4,​4'-​biphenyldicarboxylicacid
其他名称:H2mbpdc ; H2Me-BPDC ; CH3-BPDC;2-​Methyl[1,​1'-​biphenyl]​-​4,​4'-​dicarboxylic acid
CAS:1186048-28-1
结构信息
分子式 C15H12O4 分子量 256.25338
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Mn(mbpdc)​(phen)​] [r2]; PCN-700-Me [r3]; UIO-67-Me [r4]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Burrows, Andrew D.; Frost, Christopher G.; Mahon, Mary F.; Richardson, Christopher; Chem. Commun. 2009, (28), 4218-4220, DOI: 10.1039/b906170c ; Sulfur-​tagged metal-​organic frameworks and their post-​synthetic oxidation
2) Xu, Guang-Hui; Ma, Yu; Wang, Kun; Wang, Xuan; Gao, En-Qing; J. Mole.Struct. 2013, 1040, 25-32, DOI: 10.1016/j.molstruc.2013.01.074 ; Synthesis, structure, and magnetic properties of manganese-​organic frameworks of 2-​methyl-​4,​4'-​biphenyldicarboxylate with different auxiliary ligands
3) uan, Shuai; Zou, Lanfang; Li, Haixia; Chen, Ying-Pin; Qin, Junsheng; Zhang, Qiang; Lu, Weigang; Hall, Michael B.; Zhou, Hong-Cai; Angew. Chem., Int. Ed. 2016, 55(36), 10776-10780, DOI: 10.1002/anie.201604313 ; Flexible Zirconium Metal-​Organic Frameworks as Bioinspired Switchable Catalysts
4) Ruffley, Jonathan P.; Goodenough, Isabella; Luo, Tian-Yi; Richard, Melissandre; Borguet, Eric; Rosi, Nathaniel L.; Johnson, J. Karl; J. Phys. Chem. C 2019, 123, 32, 19748-19758, DOI: 10.1021/acs.jpcc.9b05574 ; Design, Synthesis, and Characterization of Metal-​Organic Frameworks for Enhanced Sorption of Chemical Warfare Agent Simulants

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2-Methyl-[1,1'-biphenyl]-4,4'-dicarboxylic acid
2-Methyl-[1,1'-biphenyl]-4,4'-dicarboxylic acid