1,4-双(二羧基苯基乙炔基)苯
1,4-Di((3,5-dicarboxyphenyl)ethynyl)benzene
CAS:957014-40-3
分子式:C26H14O8
分子量:454.38456
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产品名称：1,4-Di((3,5-dicarboxyphenyl)ethynyl)benzene
其他名称：TCB ; H4TCB ; PDEB;5,5'-(1,4-Phenylenedi-2,1-ethynediyl)bis[1,3-benzenedicarboxylic acid]
CAS：957014-40-3
3) Zhao, Jian-Feng; Li, Yi-Bao; Lin, Zong-Qiong; Xie, Ling-Hai; Shi, Nai-En; Wu, Xing-Kui; Wang, Chen; Huang, Wei; J. Phys. Chem. C 2010, 114(21), 9931-9937, DOI: 10.1021/jp1022482 ; Molecule Length Directed Self-Assembly Behavior of Tetratopic Oligomeric Phenylene-Ethynylenes End-Capped with Carboxylic Groups by Scanning Tunneling Microscopy
4) Zheng, Baishu; Yun, Ruirui; Bai, Junfeng; Lu, Zhiyong; Du, Liting; Li, Yizhi; Inorg. Chem. 2013, 52(6), 2823-2829, DOI :10.1021/ic301598n ; Expanded Porous MOF-505 Analogue Exhibiting Large Hydrogen Storage Capacity and Selective Carbon Dioxide Adsorption
其他名称：TCB ; H4TCB ; PDEB;5,5'-(1,4-Phenylenedi-2,1-ethynediyl)bis[1,3-benzenedicarboxylic acid]
CAS：957014-40-3
结构信息
| 分子式 | C26H14O8 | 分子量 | 454.38456 | ||
| 性状照片 | |||||
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料：NJU-Bai12 [r4]; UHM-8 , UHM-9 [r5]
表征图谱
参考文献
1) Daniell, Heather W.; Klotz, Eric J. F.; Odell, Barbara; Claridge, Tim D. W.; Anderson, Harry L.; Angew. Chem., Int. Ed. 2007, 46(36), 6845-6848, DOI: 10.1002/anie.200702349 ; Solid-phase synthesis of oligo(phenylene ethynylene) rotaxanes
2) Zhou, Hui; Dang, Hung; Yi, Ji-Hyun; Nanci, Antonio; Rochefort, Alain; Wuest, James D.; Journal of the American Chemical Society 2007, 129(45), 13774-13775, DOI: 10.1021/ja0742535 ; Frustrated 2D Molecular Crystallization5) Frahm, Daniela; Hoffmann, Frank; Froeba, Michael; Cryst. Growth & Des. 2014, 14(4), 1719-1725, DOI: 10.1021/cg4018536 ; Two Metal-Organic Frameworks with a Tetratopic Linker: Solvent-Dependent Polymorphism and Postsynthetic Bromination
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