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1,3,5-三(4-乙烯苯基)苯
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1,3,5-三(4-乙烯苯基)苯
4,​4''-​diethenyl-​5'-​(4-​ethenylphenyl)​-1,​1':3',​1''-​Terphenyl
CAS:944155-02-6 分子式:C30H24 分子量:384.51156
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产品名称:1,​3,​5-​Tris(4-​ethenylphenyl)​benzene
其他名称:TEPB; TVPB;4,​4''-​Diethenyl-​5'-​(4-​ethenylphenyl)​-​1,​1':3',​1''-​terphenyl; 1,​3,​5-​Tri(4-​vinylphenyl)​benzene
CAS:944155-02-6
结构信息
分子式 C30H24 分子量 384.51156
性状照片  
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料:
2) 可用于合成luminescent microporous org. polymers LMOP-1,2,3 [r2]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Terenziani, Francesca; Le Droumaguet, Celine; Katan, Claudine; Mongin, Olivier; Blanchard-Desce, Mireille; ChemPhysChem 2007, 8(5), 723-734, DOI: 10.1002/cphc.200600689 ; Effect of branching on two-​photon absorption in triphenylbenzene derivatives
2) Sun, Libo; Liang, Zhiqiang; Yu, Jihong; Xu, Ruren; Polym. Chem. 2013, 4(6), 1932-1938, DOI: 10.1039/c2py21034g ; Luminescent microporous organic polymers containing the 1,​3,​5-​tri(4-​ethenylphenyl)​benzene unit constructed by Heck coupling reaction
3) Gopalakrishnan, Deepti; Dichtel, William R.; Journal of the American Chemical Society 2013, 135(22), 8357-8362, DOI: 10.1021/ja402668e ; Direct Detection of RDX Vapor Using a Conjugated Polymer Network
4) Li, Cunyao; Sun, Keju; Wang, Wenlong; Yan, Li; Sun, Xueping; Wang, Yuqing; Xiong, Kai; Zhan, Zhuangping; Jiang, Zheng; Ding, Yunjie; J. Catal. 2017, 353, 123-132, DOI: 10.1016/j.jcat.2017.07.022 ; Xantphos doped Rh​/POPs-​PPh3 catalyst for highly selective long-​chain olefins hydroformylation: Chemical and DFT insights into Rh location and the roles of Xantphos and PPh3

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1,3,5-三(4-乙烯苯基)苯
1,3,5-三(4-乙烯苯基)苯