产品名称:1,3,5-Tris(4-ethenylphenyl)benzene其他名称:TEPB; TVPB;4,4''-Diethenyl-5'-(4-ethenylphenyl)-1,1':3',1''-terphenyl; 1,3,5-Tri(4-vinylphenyl)benzene CAS:944155-02-6
结构信息
分子式 |
C30H24 |
分子量 |
384.51156 |
性状照片 |
|
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料:
2) 可用于合成luminescent microporous org. polymers LMOP-1,2,3 [r2]
表征图谱
参考文献
1) Terenziani, Francesca; Le Droumaguet, Celine; Katan, Claudine; Mongin, Olivier; Blanchard-Desce, Mireille; ChemPhysChem 2007, 8(5), 723-734, DOI: 10.1002/cphc.200600689 ; Effect of branching on two-photon absorption in triphenylbenzene derivatives
2) Sun, Libo; Liang, Zhiqiang; Yu, Jihong; Xu, Ruren; Polym. Chem. 2013, 4(6), 1932-1938, DOI: 10.1039/c2py21034g ; Luminescent microporous organic polymers containing the 1,3,5-tri(4-ethenylphenyl)benzene unit constructed by Heck coupling reaction
3) Gopalakrishnan, Deepti; Dichtel, William R.; Journal of the American Chemical Society 2013, 135(22), 8357-8362, DOI: 10.1021/ja402668e ; Direct Detection of RDX Vapor Using a Conjugated Polymer Network
4) Li, Cunyao; Sun, Keju; Wang, Wenlong; Yan, Li; Sun, Xueping; Wang, Yuqing; Xiong, Kai; Zhan, Zhuangping; Jiang, Zheng; Ding, Yunjie; J. Catal. 2017, 353, 123-132, DOI: 10.1016/j.jcat.2017.07.022 ; Xantphos doped Rh/POPs-PPh3 catalyst for highly selective long-chain olefins hydroformylation: Chemical and DFT insights into Rh location and the roles of Xantphos and PPh3