MOF-74(Ni)
MOF-74(Ni)
CAS:882977-00-6
分子式:C8H6Ni2O8
分子量:347.52
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材料名称：MOF-74(Ni)
其他名称：Ni-MOF-74 ; Ni-DOBDC; CPO-27(Ni); Ni2(dhtp)
CAS：882977-00-6
其他名称：Ni-MOF-74 ; Ni-DOBDC; CPO-27(Ni); Ni2(dhtp)
CAS：882977-00-6
结构信息
| 单位分子式 | C8H4O8Ni2 | 单位分子量 | 345.49936 | ||
| 配位金属 | Ni | 配体 | 2,5-二羟基对苯二甲酸 (CAS: 610-92-4) | ||
| 孔径 | 1.2 nm 垂直孔道 | 孔容 | 0.6 cm3/g | ||
| 比表面 | BET比表面 ＞700 m2/g | ||||
| 模拟结构 |   |
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产品性状
| 产品形貌 | 褐绿色粉末 Brown Green Powders |  |
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| 粒径 | 3-5um 不规则块状颗粒 | |||
稳定性
1) MOF-74(Ni) 在密闭干燥条件下稳定数周；在空气中尤其是潮湿气氛中（湿度>10%）易吸湿分解，水溶液中不稳定；
2) 热分解温度约300度
2) 热分解温度约300度
保存和活化方法
1) 常温或低温条件下，干燥密封保存
2）建议使用前150度（真空）烘箱活化6小时
2）建议使用前150度（真空）烘箱活化6小时
其他特性
荧光:NA
应用领域
1) 储气材料（二氧化碳、甲烷）和吸附材料
2) MOF-74在水溶液中分解，可作为药物载体进行药物吸附和缓释
2) MOF-74在水溶液中分解，可作为药物载体进行药物吸附和缓释
表征图谱
参考文献
1) Dietzel, Pascal D. C.; Panella, Barbara; Hirscher, Michael; Blom, Richard; Fjellvag, Helmer; Chem. Commun., 2006, 959-961, DOI: 10.1039/B515434K ; Hydrogen adsorption in a nickel based coordination polymer with open metal sites in the cylindrical cavities of the desolvated framework
2) Zhao, Shenlong; Tan, Chunhui; He, Chun-Ting; An, Pengfei; Xie, Feng; Jiang, Shuai; Zhu, Yanfei; Wu, Kuang-Hsu; Zhang, Binwei ; Li, Haijing; Zhang, Jing; Chen, Yuan ; Liu, Shaoqin; Dong, Juncai ; Tang, Zhiyong; Nat. Energy 2020, 5, 881–890 , DOI: 10.1038/s41560-020-00709-1 ;
Structural transformation of highly active metal-organic framework electrocatalysts during the oxygen evolution reaction
3) Wang, Xiaolu; Xiao, Hai ; Li, Ang; Li, Zhi; Liu, Shoujie; Zhang, Qinghua; Gong, Yue; Zheng, Lirong; Zhu, Youqi; Chen, Chen ; Wang, Dingsheng ; Peng, Qing; Gu, Lin ; Han, Xiaodong ; Li, Jun ; Li, Yadong; J. Am. Chem. Soc. 2018, 140, 45, 15336–15341, DOI: 10.1021/jacs.8b08744 ; Constructing NiCo/Fe3O4 Heteroparticles within MOF-74 for Efficient Oxygen Evolution Reactions
4) Sun, Dengrong; Sun, Fangxiang; Deng, Xiaoyu; Li, Zhaohui; Inorg. Chem. 2015, 54(17), 8639-8643, DOI: 10.1021/acs.inorgchem.5b01278 ; Mixed-Metal Strategy on Metal-Organic Frameworks (MOFs) for Functionalities Expansion: Co Substitution Induces Aerobic Oxidation of Cyclohexene over Inactive Ni-MOF-74【文献解读】；
5）Jian Zheng, Rama S. Vemuri, Luis Estevez, Phillip K. Koech, Tamas Varga, Donald M. Camaioni, Thomas A. Blake, B. Peter McGrail, Radha Kishan Motkuri; Journal of the American Chemical Society, 2017, 139, 10601-10604; DOI：10.1021/jacs.7b04872; Pore-Engineered Metal−Organic Frameworks with Excellent Adsorption of Water and Fluorocarbon Refrigerant for Cooling Applications【文献解读】；
6) Siru Chen, Ming Xue,* Yanqiang Li, Ying Pan, Liangkui Zhu and Shilun Qiu*; J. Mater. Chem. A, 2015,3, 20145-20152; doi: .1039/C5TA02557E; Rational design and synthesis of NixCo3−xO4 nanoparticles derived from multivariate MOF-74 for supercapacitors†【文献解读】；
7) Matthew T. Kapelewski, Tomče Runčevski, Jacob D. Tarver, Henry Z. H. Jiang, Katherine E. Hurst, Philip A. Parilla, Anthony Ayala, Thomas Gennett, Stephen A. FitzGerald, Craig M. Brown, Jeffrey R. Long*; Chemistry of Materials, 2018, 30, 8179-8189; DOI：10.1021/acs.chemmater.8b03276; Record High Hydrogen Storage Capacity in the Metal-Organic Framework Ni₂(m-dobdc) at Near-Ambient Temperatures【文献解读】
