MIL-101(Cr)
MIL-101(Cr)
CAS:869288-09-5
分子式:C24H16Cr3FO15
分子量:719.36
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材料名称：MIL-101(Cr)
其他名称：NA
CAS：869288-09-5
其他名称：NA
CAS：869288-09-5
结构信息
| 单位分子式 | C24H12O15FCr3 | 单位分子量 | 715.33 | ||
| 配位金属 | Cr | 配体 | 对苯二甲酸（CAS：100-21-0） | ||
| 孔径 | 窗口: 1.2-1.6nm;孔径: 2.9-3.4nm | 孔容 | 2.0-2.4 cm3/g | ||
| 比表面 | BET比表面 2800-3200 m2/g | ||||
| 模拟结构 |   |
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产品性状
| 产品形貌 | 灰绿色粉末 |  |
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| 粒径 |
500-800nm |
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稳定性
1) MIL-101(Cr)在空气中非常稳定，可稳定放置数月。热分解温度>300℃。
2) 水溶液中稳定，耐强酸弱碱 PH 1-12
2) 水溶液中稳定，耐强酸弱碱 PH 1-12
3) 耐受F离子
保存和活化方法
1) 常温或低温条件下，干燥密封保存
2) 气体吸附实验前，建议使用前85度（真空）烘箱活化10小时
2) 气体吸附实验前，建议使用前85度（真空）烘箱活化10小时
其他特性
荧光：NA
应用领域
1) 储气材料和吸附材料
表征图谱
参考文献
1) G. Férey, C. Mellot-Draznieks, C. Serre, F. Millange, J. Dutour, S. Surblé, I. Margiolaki, Science 2005, 309(5743), 2040-2042, DOI: 10.1126/science.1116275 ; A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area;
2）Lomig Hamon, Christian Serre, Thomas Devic, Thierry Loiseau, Franck Millange, Gérard Férey, Guy De Weireld; Journal of the American Chemical Society, 2009, 131, 25; DOI：10.1021/ja901587t; Comparative Study of Hydrogen Sulfide Adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) Metal-Organic Frameworks at Room Temperature.【文献解读】；
3）Young Kyu Hwang, Do-Young Hong, Jong-San Chang, Sung Hwa Jhung, You-Kyong Seo, Jinheung Kim, Alexandre Vimont, Marco Daturi, Christian Serre, Gerard Ferey; Angewandte Chemie International Edition, 2008, 47, 4144-4148; DOI：10.1002/anie.200705998; Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation【文献解读】；
4）Philip L. Llewellyn, Sandrine Bourrelly, Christian Serre, Alexandre Vimont, Marco Daturi, Lomig Hamon, Guy De Weireld, Jong-San Chang, Do-Young Hong, Young Kyu Hwang, Sung Hwa Jhung, Gérard Ferey; Langmuir, 2008, 24, 14, 7245-7250; DOI：10.1021/la800227x; High Uptakes of CO₂ and CH₄ in Mesoporous Metal-Organic Frameworks MIL-100 and MIL-101【文献解读】；
5）Sara Sorribas, Patricia Gorgojo, Carlos Tellez, Joaquín Coronas, Andrew G. Livingston; Journal of the American Chemical Society, 2013, 135, 15201-15208; DOI：10.1021/ja407665w; High Flux Thin Film Nanocomposite Membranes Based on Metal−Organic Frameworks for Organic Solvent Nanofiltration【文献解读】；
6）Enamul Haque, Ji Eun Lee, In Tae Jang, Young Kyu Hwang, Jong-San Chang, Jonggeon Jegal, Sung Hwa Jhung; Journal of Hazardous Materials, 2010, 181, 535-542; DOI：10.1016/j.jhazmat.2010.05.047; Adsorptive removal of methyl orange from aqueous solution with metal-organic frameworks, porous chromium-benzenedicarboxylates【文献解读】；
7）Sung Hwa Jhung, Jin-Ho Lee, Ji Woong Yoon, Christian Serre, Gérard Férey, Jong-San Chang*; Advanced Materials, 2007, 19, 121-124; DOI：10.1002/adma.200601604; Microwave Synthesis of Chromium Terephthalate MIL‐101 and Its Benzene Sorption Ability【文献解读】；
8）Lomig Hamon, Christian Serre, Thomas Devic, Thierry Loiseau, Franck Millange, Gérard Férey, Guy De Weireld；Journal of the American Chemical Society, 2009, Volume 131, Issue 25；DOI：10.1021/ja901587t；Comparative Study of Hydrogen Sulfide Adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) Metal-Organic Frameworks at Room Temperature【文献解读】；
9）Cheng-Xiong Yang and Xiu-Ping Yan*;Analytical Chemistry, 2011, 83, 7144–7150; DOI：10.1021/ac201517c; Metal-Organic Framework MIL-101(Cr) for High-Performance Liquid Chromatographic Separation of Substituted Aromatics【文献解读】；
