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5',5''-bis(4-formylphenyl)-2',2'',4',4'',6',6''-hexamethyl-[1,1':3',1'':3'',1'''-Quaterphenyl]-4,4'''-dicarboxaldehyde
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5',5''-bis(4-formylphenyl)-2',2'',4',4'',6',6''-hexamethyl-[1,1':3',1'':3'',1'''-Quaterphenyl]-4,4'''-dicarboxaldehyde
5',5''-bis(4-formylphenyl)-2',2'',4',4'',6',6''-hexamethyl-[1,1':3',1'':3'',1'''-Quaterphenyl]-4,4'''-dicarboxaldehyde
CAS:868046-55-3 分子式:C46H38O4 分子量:654.79152
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产品名称:3,​3',​5,​5'-​Tetrakis(4-​formylphenyl)​bimesityl
其他名称:TFBM;[1,​1':3',​1'':3'',​1'''-​Quaterphenyl]​-​4,​4'''-​dicarboxaldehyde, 5',​5''-​bis(4-​formylphenyl)​-​2',​2'',​4',​4'',​6',​6''-​hexamethyl-
CAS:868046-55-3
结构信息
分子式 C46H38O4 分子量 654.79152
性状照片  
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料:PCOF-1, PCOF-2 [r3];
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Moorthy, Jarugu Narasimha; Natarajan, Ramalingam; Venugopalan, Paloth; J. Org. Chem. 2005, 70(21), 8568-8571, DOI: 10.1021/jo051205z ; Three-​Dimensional Four-​Connecting Organic Scaffolds with a Twist: Synthesis and Self-​Assembly
2) Moorthy, Jarugu Narasimha; Venkatakrishnan, Parthasarathy; Natarajan, Palani; Lin, Zhenghuan; Chow, Tahsin J.; J. Org. Chem. 2010, 75(8), 2599-2609, DOI: 10.1021/jo1001565 ; Nondoped Pure-​Blue OLEDs Based on Amorphous Phenylenevinylene-​Functionalized Twisted Bimesitylenes
3) Liu, Yong; Yan, Xiaodong; Li, Tao; Zhang, Wen-Da; Fu, Qiu-Ting; Lu, Hui-Shu; Wang, Xuan; Gu, Zhi-Guo; New. J. Chem. 2019, 43(43), 16907-16914, DOI: 10.1039/c9nj04017j ; Three-​dimensional porphyrin-​based covalent organic frameworks with tetrahedral building blocks for single-​site catalysis
4) Liu, Yong; Yan, Xiaodong; Lu, Hui-Shu; Zhang, Wen-Da; Shi, Ya-Xiang; Gu, Zhi-Guo; Sensors and Actuators, B 2020, 323, 128708, DOI: 10.1016/j.snb.2020.128708 ; A three-​dimensional covalent organic framework with turn-​on luminescence for molecular decoding of volatile organic compounds

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5',5''-bis(4-formylphenyl)-2',2'',4',4'',6',6''-hexamethyl-[1,1':3',1'':3'',1'''-Quaterphenyl]-4,4'''-dicarboxaldehyde
5',5''-bis(4-formylphenyl)-2',2'',4',4'',6',6''-hexamethyl-[1,1':3',1'':3'',1'''-Quaterphenyl]-4,4'''-dicarboxaldehyde