产品名称:3,3',5,5'-Tetrakis(4-formylphenyl)bimesityl其他名称:TFBM;[1,1':3',1'':3'',1'''-Quaterphenyl]-4,4'''-dicarboxaldehyde, 5',5''-bis(4-formylphenyl)-2',2'',4',4'',6',6''-hexamethyl- CAS:868046-55-3
结构信息
分子式 |
C46H38O4 |
分子量 |
654.79152 |
性状照片 |
|
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料:PCOF-1, PCOF-2 [r3];
表征图谱
参考文献
1) Moorthy, Jarugu Narasimha; Natarajan, Ramalingam; Venugopalan, Paloth; J. Org. Chem. 2005, 70(21), 8568-8571, DOI: 10.1021/jo051205z ; Three-Dimensional Four-Connecting Organic Scaffolds with a Twist: Synthesis and Self-Assembly
2) Moorthy, Jarugu Narasimha; Venkatakrishnan, Parthasarathy; Natarajan, Palani; Lin, Zhenghuan; Chow, Tahsin J.; J. Org. Chem. 2010, 75(8), 2599-2609, DOI: 10.1021/jo1001565 ; Nondoped Pure-Blue OLEDs Based on Amorphous Phenylenevinylene-Functionalized Twisted Bimesitylenes
3) Liu, Yong; Yan, Xiaodong; Li, Tao; Zhang, Wen-Da; Fu, Qiu-Ting; Lu, Hui-Shu; Wang, Xuan; Gu, Zhi-Guo; New. J. Chem. 2019, 43(43), 16907-16914, DOI: 10.1039/c9nj04017j ; Three-dimensional porphyrin-based covalent organic frameworks with tetrahedral building blocks for single-site catalysis
4) Liu, Yong; Yan, Xiaodong; Lu, Hui-Shu; Zhang, Wen-Da; Shi, Ya-Xiang; Gu, Zhi-Guo; Sensors and Actuators, B 2020, 323, 128708, DOI: 10.1016/j.snb.2020.128708 ; A three-dimensional covalent organic framework with turn-on luminescence for molecular decoding of volatile organic compounds