2,5,8,11-Tetra-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-perylene
CAS:853377-12-5
分子式:C44H56B4O8
分子量:756.15464
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产品名称：2,5,8,11-Tetra-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-perylene
其他名称：perylene-2,5,8,11-(Bpin)4 ; PeTTB;2,2',2'',2'''-(2,5,8,11-Perylenetetrayl)tetrakis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane]; 2,5,8,11-Tetra-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-perylene; 2,5,8,11-Tetrakis-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)perylene
CAS：853377-12-5
3) Tran, Ly D.; Ma, Jialiu; Wong-Foy, Antek G.; Matzger, Adam J.; Chem.-Euro. J. 2016, 22(16), 5509-5513, DOI: 10.1002/chem.201600526 ; A Perylene-Based Microporous Coordination Polymer Interacts Selectively with Electron-Poor Aromatics
4) Li, Lianwei; Cai, Zhengxu; Wu, Qinghe; Lo, Wai-Yip; Zhang, Na; Chen, Lin X.; Yu, Luping; Journal of the American Chemical Society 2016, 138(24), 7681-7686, DOI: 10.1021/jacs.6b03472 ; Rational Design of Porous Conjugated Polymers and Roles of Residual Palladium for Photocatalytic Hydrogen Production
其他名称：perylene-2,5,8,11-(Bpin)4 ; PeTTB;2,2',2'',2'''-(2,5,8,11-Perylenetetrayl)tetrakis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane]; 2,5,8,11-Tetra-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-perylene; 2,5,8,11-Tetrakis-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)perylene
CAS：853377-12-5
结构信息
| 分子式 | C44H56B4O8 | 分子量 | 756.15464 | ||
| 性状照片 | |||||
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料：Porous Conjugated Polymers: PCP-3x [r4]; semiconducting microporous framework: SMF-1, SMF-2 [r5]
表征图谱
参考文献
1) Coventry, David N.; Batsanov, Andrei S.; Goeta, Andres E.; Howard, Judith A. K.; Marder, Todd B.; Perutz, Robin N.; Chem. Commun. 2005, (16), 2172-2174, DOI: 10.1039/b501778e ; Selective Ir-catalysed borylation of polycyclic aromatic hydrocarbons: structures of naphthalene-2,6-bis(boronate), pyrene-2,7-bis(boronate) and perylene-2,5,8,11-tetra(boronate) esters
2) Della Pia, Ada; Riello, Massimo; Floris, Andrea; Stassen, Daphne; Jones, Tim S.; Bonifazi, Davide; De Vita, Alessandro; Costantini, Giovanni; ACS Nano 2014, 8(12), 12356-12364, DOI: 10.1021/nn505063w ; Anomalous Coarsening Driven by Reversible Charge Transfer at Metal-Organic Interfaces5) Xu, Jie; Tang, Weiqiang; Yu, Fengtao; Zhao, Shuangliang; Niu, Dongfang; Zhang, Xinsheng; Xin, Zhong; Chen, Renjie; J. Mater. Chem. A 2020, 8(36), 19001-19010, DOI: 10.1039/d0ta06383e ; Trimming the π bridge of microporous frameworks for bidentate anchoring of polysulfides to stabilize lithium-sulfur batteries