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萘-​2.​6-​二(硼酸酯)
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萘-​2.​6-​二(硼酸酯)
4,4,5,5-tetramethyl-2-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)naphthalen-6-yl)-1,3,2-dioxaborolane
CAS:849543-98-2 分子式:C22H30B2O4 分子量:380.0932
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产品名称:naphthalene-​2,​6-​bis(boronate)
其他名称:;2,​2'-​(2,​6-​Naphthalenediyl)​bis[4,​4,​5,​5-​tetramethyl-​1,​3,​2-​dioxaborolane] ; ​2,​6-​Bis(4,​4,​5,​5-​tetramethyl-​1,​3,​2-​dioxaborolan-​2-​yl)​naphthalene
CAS:849543-98-2
结构信息
分子式 C22H30B2O4 分子量 380.0932
性状照片  
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料:Carbon Nanorings [13]​CPPN [r2]; polymer semiconductors: PDPP-FNF
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) McCulloch, Iain; Bailey, Clare; Giles, Mark; Heeney, Martin; Love, Iain; Shkunov, Maxim; Sparrowe, David; Tierney, Steve; Chem. Mater. 2005, 17(6), 1381-1385, DOI: 10.1021/cm047754n ; Influence of Molecular Design on the Field-​Effect Transistor Characteristics of Terthiophene Polymers
2) Omachi, Haruka; Segawa, Yasutomo; Itami, Kenichiro; Org. Lett. 2011, 13(9), 2480-2483, DOI: 10.1021/ol200730m ; Synthesis and Racemization Process of Chiral Carbon Nanorings: A Step toward the Chemical Synthesis of Chiral Carbon Nanotubes
3) Li, Weiwei; Roelofs, W. S. Christian; Wienk, Martijn M.; Janssen, Rene A. J.; Journal of the American Chemical Society 2012, 134(33), 13787-13795, DOI: 10.1021/ja305358z ; Enhancing the Photocurrent in Diketopyrrolopyrrole-​Based Polymer Solar Cells via Energy Level Control
4) Kim, Gyoungsik; Kang, Seok-Ju; Dutta, Gitish K.; Han, Young-Kyu; Shin, Tae Joo; Noh, Yong-Young; Yang, Changduk; Journal of the American Chemical Society 2014, 136(26), 9477-9483, DOI: 10.1021/ja504537v ; A Thienoisoindigo-​Naphthalene Polymer with Ultrahigh Mobility of 14.4 cm2​/V·s That Substantially Exceeds Benchmark Values for Amorphous Silicon Semiconductors

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萘-​2.​6-​二(硼酸酯)
萘-​2.​6-​二(硼酸酯)