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4,4'-二苯基二硫醇
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4,4'-二苯基二硫醇
Biphenyl-4,4'-dithiol
CAS:6954-27-4 分子式:C12H10S2 分子量:218.3378
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产品名称:[1,​1'-​Biphenyl]​-​4,​4'-​dithiol
其他名称:H2bpdt;4,​4'-​Biphenyldithiol; 4,​4'-​Dimercaptobiphenyl; 4,​4'-​Dimercaptodiphenyl; 4,​4'-​Diphenyldithiol
CAS:6954-27-4
结构信息
分子式 C12H10S2 分子量 218.3378
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Cd(en)​3]​[Cd(bpdt)​2]​(en)​ [r1]; Conjugated Thiol polymers;
2)可作为高分子交联剂或生物交联剂
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Louvain, Nicolas; Takashima, Yohei; Kitagawa, Susumu; Furukawa, Shuhei; New J. Chemistry . 2011, 35(6), 1265-1269, DOI: 10.1039/c1nj20042a ; Thermodynamically controlled coordination-​engineering of novel 2D cadmium thiolate coordination polymers
2) Andres, Ronald P.; Bein, Thomas; Dorogi, Matt; Feng, Sue; Henderson, Jason I.; Kubiak, Clifford P.; Mahoney, William; Osifchin, Richard G.; Reifenberger, R.; Science 1996, 272(5266), 1323-1325, DOI: 10.1126/science.272.5266.1323 ; "Coulomb staircase" at room temperature in a self-​assembled molecular nanostructure
3) Reddy, Pramod; Jang, Sung-Yeon; Segalman, Rachel A.; Majumdar, Arun; Science 2007, 315(5818), 1568-1571, DOI: 10.1126/science.1137149 ; Thermoelectricity in Molecular Junctions
4) Tour, James M.; Jones, LeRoy, II; Pearson, Darren L.; Lamba, Jaydeep J. S.; Burgin, Timothy P.; Whitesides, George M.; Allara, David L.; Parikh, Atul N.; Atre, Sundar; J. Am. Chem. Soc. 1995, 117(37), 9529-9534, DOI: 10.1021/ja00142a021 ; Self-​Assembled Monolayers and Multilayers of Conjugated Thiols, α,​ω-​Dithiols, and Thioacetyl-​Containing Adsorbates. Understanding Attachments between Potential Molecular Wires and Gold Surfaces

5) Dadosh, Tali; Gordin, Yoav; Krahne, Roman; Khivrich, Ilya; Mahalu, Diana; Frydman, Veronica; Sperling, Joseph; Yacoby, Amir; Bar-Joseph, Israel; Nature 2005, 436(7051), 677-680, DOI: 10.1038/nature03898 ; Measurement of the conductance of single conjugated molecules

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4,4'-二苯基二硫醇
4,4'-二苯基二硫醇