CAS 6954-27-4|H2bpdt|CHEMSOON-MOF/COF材料专业供应商

产品名称：[1,1'-Biphenyl]-4,4'-dithiol
其他名称：H2bpdt;4,4'-Biphenyldithiol; 4,4'-Dimercaptobiphenyl; 4,4'-Dimercaptodiphenyl; 4,4'-Diphenyldithiol
CAS：6954-27-4

结构信息

分子式	C12H10S2		分子量	218.3378
性状照片

性质说明

1) 可溶于DMF、DMSO等
2) 室温密封保存

合成应用

1) 可作为配体用于合成MOF材料：[Cd(en)3][Cd(bpdt)2](en) [r1]; Conjugated Thiol polymers;

2）可作为高分子交联剂或生物交联剂

表征图谱

HNMR

FTIR

HPLC

参考文献

1) Louvain, Nicolas; Takashima, Yohei; Kitagawa, Susumu; Furukawa, Shuhei; New J. Chemistry . 2011, 35(6), 1265-1269, DOI: 10.1039/c1nj20042a ; Thermodynamically controlled coordination-engineering of novel 2D cadmium thiolate coordination polymers

2) Andres, Ronald P.; Bein, Thomas; Dorogi, Matt; Feng, Sue; Henderson, Jason I.; Kubiak, Clifford P.; Mahoney, William; Osifchin, Richard G.; Reifenberger, R.; Science 1996, 272(5266), 1323-1325, DOI: 10.1126/science.272.5266.1323 ; "Coulomb staircase" at room temperature in a self-assembled molecular nanostructure

3) Reddy, Pramod; Jang, Sung-Yeon; Segalman, Rachel A.; Majumdar, Arun; Science 2007, 315(5818), 1568-1571, DOI: 10.1126/science.1137149 ; Thermoelectricity in Molecular Junctions

4) Tour, James M.; Jones, LeRoy, II; Pearson, Darren L.; Lamba, Jaydeep J. S.; Burgin, Timothy P.; Whitesides, George M.; Allara, David L.; Parikh, Atul N.; Atre, Sundar; J. Am. Chem. Soc. 1995, 117(37), 9529-9534, DOI: 10.1021/ja00142a021 ; Self-Assembled Monolayers and Multilayers of Conjugated Thiols, α,ω-Dithiols, and Thioacetyl-Containing Adsorbates. Understanding Attachments between Potential Molecular Wires and Gold Surfaces

5) Dadosh, Tali; Gordin, Yoav; Krahne, Roman; Khivrich, Ilya; Mahalu, Diana; Frydman, Veronica; Sperling, Joseph; Yacoby, Amir; Bar-Joseph, Israel; Nature 2005, 436(7051), 677-680, DOI: 10.1038/nature03898 ; Measurement of the conductance of single conjugated molecules

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