1H-Imidazole, 1,1'-(1,6-hexanediyl)bis-
1H-Imidazole, 1,1'-(1,6-hexanediyl)bis-
CAS:69506-88-3
分子式:C12H18N4
分子量:218.29812
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产品名称：1,6-Bis(imidazol-1-yl)hexane
其他名称：bimh; 1,1'-(1,6-Hexanediyl)bis(imidazole); 1,1'-(Hexane-1,6-diyl)diimidazole; 1,6-Bis(1H-imidazol-1-yl)hexane; 1,6-Bis(N-imidazolyl)hexane;
CAS：69506-88-3
3) Nakajima, Hiromitsu; Ohno, Hiroyuki; Polymer 2005, 46(25), 11499-11504, DOI: 10.1016/j.polymer.2005.10.005 ; Preparation of thermally stable polymer electrolytes from imidazolium-type ionic liquid derivatives
4) Qi, Yan; Luo, Feng; Che, Yunxia; Zheng, Jimin; Cryst. Growth & Des. 2008, 8(2), 606-611, DOI: 10.1021/cg700758c ; Hydrothermal synthesis of metal-organic frameworks based on aromatic polycarboxylate and flexible bis(imidazole) ligands
其他名称：bimh; 1,1'-(1,6-Hexanediyl)bis(imidazole); 1,1'-(Hexane-1,6-diyl)diimidazole; 1,6-Bis(1H-imidazol-1-yl)hexane; 1,6-Bis(N-imidazolyl)hexane;
CAS：69506-88-3
结构信息
| 分子式 | C12H18N4 | 分子量 | 218.29812 | ||
| 性状照片 | |||||
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Co(bimh)(2,4'-bpdc)] [r5]
表征图谱
参考文献
1) van Pouderoyen, Gertie; den Blaauwen, Tanneke; Reedijk, Jan; Canters, Gerard W.; Biochemistry 1996, 35(40), 13205-13211, DOI: 10.1021/BI960931G ; Dimerization of a His117Gly Azurin Mutant by External Addition of 1,ω-Di(imidazol-1-yl)alkanes
2) hoji, Osami; Okada, Saori; Satake, Akiharu; Kobuke, Yoshiaki; Journal of the American Chemical Society 2005, 127(7), 2201-2210, DOI: 10.1021/ja0445746 ; Coordination Assembled Rings of Ferrocene-Bridged Trisporphyrin with Flexible Hinge-like Motion: Selective Dimer Ring Formation, Its Transformation to Larger Rings, and Vice Versa5) Liu, Yang; Qi, Yan; Su, Yan-Hua; Zhao, Fang-Hua; Che, Yun-Xia; Zheng, Ji-Min; CrystEngComm 2010, 12(10), 3283-3290, DOI: 10.1039/b925829a ; Five novel cobalt coordination polymers: effect of metal-ligand ratio and structure characteristics of flexible bis(imidazole) ligands
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