产品名称:2,2'-(2,7-Pyrenediyl)bis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane]其他名称:pyrene-2,7-(Bpin)2; CAS:688756-58-3
结构信息
分子式 |
C28H32B2O4 |
分子量 |
454.17328 |
性状照片 |
|
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料:
表征图谱
参考文献
1) Zheng, Xiaolai; Mulcahy, Mary E.; Horinek, Dominik; Galeotti, Francesco; Magnera, Thomas F.; Michl, Josef; Journal of the American Chemical Society 2004, 126(14), 4540-4542, DOI: 10.1021/ja039482f ; Dipolar and Nonpolar Altitudinal Molecular Rotors Mounted on an Au(111) Surface
2) Coventry, David N.; Batsanov, Andrei S.; Goeta, Andres E.; Howard, Judith A. K.; Marder, Todd B.; Perutz, Robin N.; Chem. Commun. DOI: 10.1039/b501778e ; Selective Ir-catalysed borylation of polycyclic aromatic hydrocarbons: structures of naphthalene-2,6-bis(boronate), pyrene-2,7-bis(boronate) and perylene-2,5,8,11-tetra(boronate) esters
3) Crawford, Andrew G.; Dwyer, Austin D.; Liu, Zhiqiang; Steffen, Andreas; Beeby, Andrew; Palsson, Lars-Olof; Tozer, David J.; Marder, Todd B.; Journal of the American Chemical Society 2011, 133(34), 13349-13362, DOI: 10.1021/ja2006862 ; Experimental and Theoretical Studies of the Photophysical Properties of 2- and 2,7-Functionalized Pyrene Derivatives
4) Evans, Austin M.; Bradshaw, Nathan P.; Litchfield, Brian; Strauss, Michael J.; Seckman, Bethany; Ryder, Matthew R.; Castano, Ioannina; Gilmore, Christopher; Gianneschi, Nathan C.; Mulzer, Catherine R.; Hersam, Mark C.; Dichtel, William R.; Adv. Mater. 2020, 32(42), 2004205, DOI: 10.1002/adma.202004205 ; High-Sensitivity Acoustic Molecular Sensors Based on Large-Area, Spray-Coated 2D Covalent Organic Frameworks