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2,2′-(2,7-Pyrenediyl)bis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane]
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2,2′-(2,7-Pyrenediyl)bis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane]
1,3,2-Dioxaborolane, 2,2'-(2,7-pyrenediyl)bis[4,4,5,5-tetramethyl-
CAS:688756-58-3 分子式:C28H32B2O4 分子量:454.173288345337
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产品名称:2,​2'-​(2,​7-​Pyrenediyl)​bis[4,​4,​5,​5-​tetramethyl-​1,​3,​2-​dioxaborolane]
其他名称:pyrene-​2,​7-​(Bpin)​2;
CAS:688756-58-3
结构信息
分子式 C28H32B2O4 分子量 454.17328
性状照片  
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料:
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Zheng, Xiaolai; Mulcahy, Mary E.; Horinek, Dominik; Galeotti, Francesco; Magnera, Thomas F.; Michl, Josef; Journal of the American Chemical Society 2004, 126(14), 4540-4542, DOI: 10.1021/ja039482f ; Dipolar and Nonpolar Altitudinal Molecular Rotors Mounted on an Au(111) Surface
2) Coventry, David N.; Batsanov, Andrei S.; Goeta, Andres E.; Howard, Judith A. K.; Marder, Todd B.; Perutz, Robin N.; Chem. Commun. DOI: 10.1039/b501778e ; Selective Ir-​catalysed borylation of polycyclic aromatic hydrocarbons: structures of naphthalene-​2,​6-​bis(boronate)​, pyrene-​2,​7-​bis(boronate) and perylene-​2,​5,​8,​11-​tetra(boronate) esters
3) Crawford, Andrew G.; Dwyer, Austin D.; Liu, Zhiqiang; Steffen, Andreas; Beeby, Andrew; Palsson, Lars-Olof; Tozer, David J.; Marder, Todd B.; Journal of the American Chemical Society 2011, 133(34), 13349-13362, DOI: 10.1021/ja2006862 ; Experimental and Theoretical Studies of the Photophysical Properties of 2- and 2,​7-​Functionalized Pyrene Derivatives
4) Evans, Austin M.; Bradshaw, Nathan P.; Litchfield, Brian; Strauss, Michael J.; Seckman, Bethany; Ryder, Matthew R.; Castano, Ioannina; Gilmore, Christopher; Gianneschi, Nathan C.; Mulzer, Catherine R.; Hersam, Mark C.; Dichtel, William R.; Adv. Mater. 2020, 32(42), 2004205, DOI: 10.1002/adma.202004205 ; High-​Sensitivity Acoustic Molecular Sensors Based on Large-​Area, Spray-​Coated 2D Covalent Organic Frameworks

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2,2′-(2,7-Pyrenediyl)bis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane]
2,2′-(2,7-Pyrenediyl)bis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane]