产品名称:1,3,5,7-tetrakis(4-formylphenyl)adamantane其他名称:TFPA;4,4',4'',4'''-Tricyclo[3.3.1.13,7]decane-1,3,5,7-tetrayltetrakis[benzaldehyde] CAS:645401-15-6
结构信息
分子式 |
C38H32O4 |
分子量 |
552.65828 |
性状照片 |
|
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料
2) 可用于合成 (DCFs) [r1];
3) 可用于合成 Polyaminal Networks:PAN-1 、PAN-2 [r2];
4) 可用于合成 porous poly(Schiff-base)s: PSN-DA, PSN-TAPB, PSN-TAPA, PSN-TAPM [r3]
表征图谱
参考文献
1) Duncan, Nathan C.; Hay, Benjamin P.; Hagaman, Edward W.; Custelcean, Radu; Tetrahedron 2012, 68(1), 53-64, DOI: 10.1016/j.tet.2011.10.052 ; Thermodynamic, kinetic, and structural factors in the synthesis of imine-linked dynamic covalent frameworks
2) Li, Guiyang; Zhang, Biao; Yan, Jun; Wang, Zhonggang; Macromolecules 2014, 47(19), 6664-6670, DOI: 10.1021/ma501497c ; Tetraphenyladamantane-Based Polyaminals for Highly Efficient Captures of CO2 and Organic Vapors
3) Li, Guiyang; Zhang, Biao; Yan, Jun; Wang, Zhonggang; J. Mater. Chem. A 2014, 2(44), 18881-18888,DOI: 10.1039/C4TA04429K ; Micro- and mesoporous poly(Schiff-base)s constructed from different building blocks and their adsorption behaviors towards organic vapors and CO2 gas