CAS 617706-61-3|TFPM|CHEMSOON

产品名称：4-[tris(4-formylphenyl)methyl]benzaldehyde
其他名称：四(4-甲酰基苯)甲烷；TFPM; 4,4',4'',4'''-methanetetrakis-benzaldehyde
CAS：617706-61-3

结构信息

分子式	C29H20O4		分子量	432.4667
性状照片

性质说明

1) 617706-61-3 溶于DCM、DMF、DMSO等
2) 2-8℃密封保存

合成应用

1) 可作为单体用于合成COF材料：3D-COF [r2]; (benzimidazole-linked polymer) BILP-1 [r3]; (Porous imine-linked networks)PIN-2 [r4]; 3D-OH COF [r5]; 3D-IL-COFs [r6]

表征图谱

HNMR

FTIR

HPLC

参考文献

1) Fournier, J.; Wang, X.; Wuest, J.; Canadian J. Chem. 2003, 81(5), 376-380, DOI:10.1139/V03-056 ; Derivatives of tetraphenylmethane and tetraphenylsilane: Synthesis of new tetrahedral building blocks for molecular construction

2) X. Guan, Y. Ma, H. Li, Y. Yusran, M. Xue, Q. Fang, Y. Yan, V. Valtchev, S. Qiu, J. Am. Chem. Soc. 2018, 140, 4494– 4498, DOI:10.1021/jacs.8b01320 ; Fast, Ambient Temperature and Pressure Ionothermal Synthesis of Three-Dimensional Covalent Organic Frameworks

3) Rabbani, M.; El-Kaderi, H.; Chem. Mater. 2011, 23(7), 1650-1653, DOI:10.1021/cm200411p

4) Popp, N.; Homburg, T.; Stock, N.; Senker, J.; J. Mater. Chem. A 2015, 3(36), 18492-18504, DOI:10.1039/C5TA02504D ; Porous imine-based networks with protonated imine linkages for carbon dioxide separation from mixtures with nitrogen and methane

5) Lu, Q.; Ma, Y.; Li, H.; Guan, X.; Yusran, Y.; Xue, M.; Fang, Q.; Yan, Y.; Qiu, S.; Valtchev, Valentin.; Angew. Chem., Int. Ed. 2018, 57(21), 6042-6048, DOI: 10.1002/anie.201712246

6) Guan, X.; Ma, Y.; Li, H.; Yusran, Y.; Xue, M.; Fang, Q.; Yan, Y.; Valtchev, V.; Qiu, S.; J. Am. Chem. Soc. 2018, 140, 13, 4494-4498, DOI: 10.1021/jacs.8b01320 ; Fast, Ambient Temperature and Pressure Ionothermal Synthesis of Three-Dimensional Covalent Organic Frameworks

HNMR-617706-61-3-CS013207.pdf	下载
617706-61-3-CS014173.pdf	下载
617706-61-3-CS014472.pdf	下载
617706-61-3-CS017545.pdf	下载
617706-61-3-CS017843.pdf	下载
617706-61-3-CS018014.pdf	下载

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