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1,3,5-Triazine, 2,4,6-tri-2-pyrimidinyl-
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1,3,5-Triazine, 2,4,6-tri-2-pyrimidinyl-
1,3,5-Triazine, 2,4,6-tri-2-pyrimidinyl-
CAS:60681-68-7 分子式:C15H9N9 分子量:315.292
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产品名称:1,3,5-Triazine, 2,4,6-tri-2-pyrimidinyl-
其他名称:TPymT
CAS:60681-68-7
结构信息
分子式  C15H9N9 分子量  315.292
性状照片  
性质说明
1) 可溶于水,微溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料,如:[Co(bpcam)2]ClO4·dmso·H2O [r3]; [Cd2(TPymT)​(SO4)​2(H2O)​6]​ [r4]; [Ag2(BPymTz)2] [r5]
表征图谱
HNMR
MS
FTIR
NA
HPLC
NA
参考文献
1) Case, Francis H.; Koft, Emil; Journal of the American Chemical Society 1959, 81, 905-906, DOI: 10.1021/ja01513a037 ;  The synthesis of certain substituted 1,​3,​5-​triazines containing the ferroin group
2) Lerner, E. I.; Lippard, S. J.; Journal of the American Chemical Society 1976, 98(17), 5397-5398, DOI: 10.1021/ja00433a061 ; 2,​4,​6-​Tris(2-​pyrimidyl)​- and 2,​4,​6-​tris(2-​pyridyl)​-​1,​3,​5-​triazines hydrolyze in the presence of copper(II) to form a novel bis(aryl)​carboximidato chelate complex
3) Garcia, Ana M.; Bassani, Dario M.; Lehn, Jean-Marie; Baum, Gerhard; Fenske, Dieter; Chemistry - A European Journal 1999, 5(4), 1234-1238, DOI: 10.1002/(SICI)1521-3765(19990401)5:4<1234::AID-CHEM1234>3.0.CO;2-G ;  Self-​assembly of multicomponent multimetallic lead(II) complexes of cylindrical architecture
4) Frost, Jamie M.; Kobera, Libor; Pialat, Amelie; Zhang, Yixin; Southern, Scott A.; Gabidullin, Bulat; Bryce, David L.; Murugesu, Muralee; Chem. Commun. 2016, 52(70), 10680-10683, DOI: 10.1039/C6CC04940K ; From discrete molecule, to polymer, to MOF: mapping the coordination chemistry of CdII using 113Cd solid-​state NMR
5) Safin, Damir A.; Pialat, Amelie; Leitch, Alicea A.; Tumanov, Nikolay A.; Korobkov, Ilia; Filinchuk, Yaroslav; Brusso, Jaclyn L.; Murugesu, Muralee; Chem. Commun. 2015, 51(46), 9547-9550, DOI: 10.1039/C5CC01597A ; Anion-​induced AgI self-​assemblies with electron deficient aromatic ligands: anion-​π-​system interactions as a driving force for templated coordination networks
60681-68-7-CS017173.pdf 下载
60681-68-7-CS017173-MS.pdf 下载

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1,3,5-Triazine, 2,4,6-tri-2-pyrimidinyl-
1,3,5-Triazine, 2,4,6-tri-2-pyrimidinyl-