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benzene-1,3,5- triyltris(methylene))triphosphonic acid
benzene-1,3,5- triyltris(methylene))triphosphonic acid
CAS:586372-53-4 分子式:C20H14N4 分子量:310.35196
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产品名称:1,​3,​5-​Benzenetris(phosphon​ic acid)​
其他名称:H6btmp ; H6bmt;P,​P',​P''-​[1,​3,​5-​Benzenetriyltris(met​hylene)​]​tris[phosphonic acid]​; (Benzene-​1,​3,​5-​triyltris(methylene)​)​triphosphonic acid; Mesitylenetriphospho​nic acid
CAS:586372-53-4
结构信息
分子式 C9H15O9P3 分子量 360.1314
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:Cu3(btmp)​(H2O)​ [r2]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Jaffres, P.; Villemin, D.; Montouillout, V.; Fernandez, C.; Chardon, J.; Sopkova-De Oliveira Santos, J.; Molecular Crystals and Liquid Crystals Science and Technology, A 2002, 389, 87-95, Self-​association of benzene-​1,​3,​5-​tris-​(methylenephosphonic acid)​: evidence of charge-​assisted hydrogen bonds
2) Yang, C.; Song, Y.; Yeh, Y.; Liu, Y.; Tseng, T.; Lu, K.; CrystEngComm 2011, 13(7), 2678-2686, DOI: 10.1039/c0ce00439a ; A flexible tris-​phosphonate for the design of copper and cobalt coordination polymers: unusual cage array topology and magnetic properties
3) Tang, S.; Pan, X.; Lv, X.; Yan, S.; Xu, X.; Li, L.; Zhao, X.; CrystEngCom 2013, 15(10), 1860-1873, DOI: 10.1039/c2ce26828k ; Fabrication of new metal phosphonates from tritopic trisphosphonic acid containing methyl groups and auxiliary ligands: syntheses, structures and gas adsorption properties
4) Vilela, S.; Firmino, A.; Mendes, R.; Fernandes, J.; Ananias, D.; Valente, A.; Ott, H.; Carlos, L.; Rocha, J.; Tome, J.; Almeida Paz, F.; Chem. Commun. 2013, 49(57), 6400-6402, DOI: 10.1039/c3cc42632g ; Lanthanide-​polyphosphonate coordination polymers combining catalytic and photoluminescence properties

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benzene-1,3,5- triyltris(methylene))triphosphonic acid
benzene-1,3,5- triyltris(methylene))triphosphonic acid