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[1,1'-联苯]-2,2',6,6'-四羧酸
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[1,1'-联苯]-2,2',6,6'-四羧酸
[1,1'-Biphenyl]-2,2',6,6'-tetracarboxylicacid
CAS:4371-27-1 分子式:C16H10O8 分子量:330.2458
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产品名称:[1,1'-Biphenyl]-2,2',6,6'-tetracarboxylicacid
其他名称:2,​2',​6,​6'-H4BPTC ; 2,​2',​6,​6'-H4bta;
CAS:4371-27-1
结构信息
分子式 C16H10O8 分子量 330.2458
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Ag4(bptc)​(bpy)​4(H2O)​]​ [r2]; [Zn4(bpta)​2(H2O)​2] [r4]; M-​BPTC (M = Mg, Sr, Ba)​ [r5]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Zhang, Yong Jian; Wang, Feijun; Zhang, Wanbin; J. Org. Chem. 2007, 72(24), 9208-9213,DOI: 10.1021/jo701469y ; Chelation-​Induced Axially Chiral Palladium Complex System with Tetraoxazoline Ligands for Highly Enantioselective Wacker-​Type Cyclization
2) Li, Bo; Zang, Shuang-Quan; Ji, Can; Hou, Hong-Wei; Mak, Thomas C. W.; Cryst. Growth & Des. 2012, 12(3), 1443-1451, DOI: 10.1021/cg2015447 ; Syntheses, Structures, and Properties of Silver-​Organic Frameworks Constructed with 1,​1'-​Biphenyl-​2,​2',​6,​6'-​tetracarboxylic Acid
3) Huang, You-Gui; Gong, Ya-Qiong; Jiang, Fei-Long; Yuan, Da-Qiang; Wu, Ming-Yan; Gao, Qiang; Wei, Wei; Hong, Mao-Chun; Cryst. Growth & Des 2007, 7(8), 1385-1387, DOI: 10.1021/cg070401r ; Formation of an Infinite Three-​Dimensional Water Network by the Hierarchic Assembly of Bilayer Water Nanotubes of Octamers
4) Chang, Ze; Zhang, Da-Shuai; Chen, Qiang; Li, Rui-Fang; Hu, Tong-Liang; Bu, Xian-He; Inorg. Chem. 2011, 50(16), 7555-7562, DOI: 10.1021/ic2004485 ; Rational Construction of 3D Pillared Metal-​Organic Frameworks: Synthesis, Structures, and Hydrogen Adsorption Properties

5) Dong, Xi-Yan; Hu, Xiao-Peng; Yao, Hong-Chang; Zang, Shuang-Quan; Hou, Hong-Wei; Mak, Thomas C. W.; Inorg. Chem. 2014, 53(22), 12050-12057, DOI: 10.1021/ic5017593 ; Alkaline Earth Metal (Mg, Sr, Ba)​-​Organic Frameworks Based on 2,​2',​6,​6'-​Tetracarboxybiphenyl for Proton Conduction

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[1,1'-联苯]-2,2',6,6'-四羧酸
[1,1'-联苯]-2,2',6,6'-四羧酸