产品名称:1,3,5-Tris[(4-bromomethyl)phenyl]benzene其他名称:TBMPB;4,4''-Bis(bromomethyl)-5'-[4-(bromomethyl)phenyl]-1,1':3',1''-terphenyl CAS:42837-44-5
结构信息
分子式 |
C27H21Br3 |
分子量 |
585.16764 |
性状照片 |
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性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为中间体用于合成MOF材料配体:
2) 可用于合成超支化聚苯[r2];
3) 可用于合成轮烷[r4];
表征图谱
参考文献
1) Voegtle, Fritz; Hohner, Gerd; Weber, Edwin; Chem. Commun. 1973, (11), 366-367, DOI: 10.1039/C39730000366 ; Novel multibridged macrocyclic systems
2) Kim, Young H.; Beckerbauer, Richard; Macromolecules (1994), 27(7), 1968-1971, DOI: 10.1021/ma00085a048 ; Role of End Groups on the Glass Transition of Hyperbranched Polyphenylene and Triphenylbenzene Derivatives
3) Zhang, Xue-Li; Guo, Cui-Ping; Yang, Qing-Yuan; Lu, Tong-Bu; Tong, Ye-Xiang; Su, Cheng-Yong; Chem. Mater. 2007, 19(19), 4630-4632, DOI: 10.1021/cm071767u ; Discrete Chiral Single-Crystal Microtubes Assembled with Honeycomb Coordination Networks Showing Structural Diversity and Borromean Topology in One Single Crystal
4) Zhang, Ji-Na; Li, Hong; Zhou, Wei; Yu, Shi-Lin; Qu, Da-Hui; Tian, He; Chem.-Eur. J. 2013, 19(50), 17192-17200, DOI: 10.1002/chem.201303026 ; Fluorescence Modulation in Tribranched Switchable [4|Rotaxanes