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(4-[2,2':6',2''-terpyridin]-4'-ylphen-Boronic acid
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(4-[2,2':6',2''-terpyridin]-4'-ylphen-Boronic acid
B-(4-[2,2':6',2''-terpyridin]-4'-ylphenyl)-Boronic acid
CAS:381218-96-8 分子式:C21H16BN3O2 分子量:353.18164
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产品名称:4-​[4'-​(2,​2':6',​2''-​terpyridil]​-​boronic acid
其他名称:trpy-​B(OH)​2;Boronic acid, (4-​[2,​2':6',​2''-​terpyridin]​-​4'-​ylphenyl)​-; B-​(4-​[2,​2':6',​2''-​Terpyridin]​-​4'-​ylphenyl)​boronic acid; 4'-​(4-​Boronatophenyl)​-​2,​2':6',​2''-​terpyridine
CAS:381218-96-8
结构信息
分子式 C21H16BN3O2 分子量 353.18164
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为中间体用于合成MOF材料配体:[Ru(trpy-​B(OH)​2)​(tb2bpy)​Cl]​(PF6) [r2]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Aspley, Catherine J.; Williams, J. A. G.; New J. Chem. 2001, 25(9), 1136-1147, DOI: 10.1039/b103062k ; Palladium-​catalysed cross-​coupling reactions of ruthenium bis-​terpyridyl complexes: strategies for the incorporation and exploitation of boronic acid functionality
2) Altobello, S.; Bignozzi, C. A.; Caramori, S.; Larramona, G.; Quici, Silvio; Marzanni, Giovanni; Lakhmiri, Rajae; J. Photochem. Photobio., A 2004), 166(1-3), 91-98, DOI: 10.1016/j.jphotochem.2004.04.029 ; Sensitization of TiO2 with ruthenium complexes containing boronic acid functions
3) Wang, Jin-Liang; Li, Xiaopeng; Lu, Xiaocun; Hsieh, I-Fan; Cao, Yan; Moorefield, Charles N.; Wesdemiotis, Chrys; Cheng, Stephen Z. D.; Newkome, George R.; Journal of the American Chemical Society 2011, 133(30), 11450-11453, DOI: 10.1021/ja203645m ; Stoichiometric Self-​Assembly of Shape-​Persistent 2D Complexes: A Facile Route to a Symmetric Supramacromolecular Spoked Wheel
4) Li, Yiming; Jiang, Zhilong; Wang, Ming; Yuan, Jie; Liu, Die; Yang, Xiaoyu; Chen, Mingzhao; Yan, Jun; Li, Xiaopeng; Wang, Pingshan; 2016, 138(31), 10041-10046, DOI: 10.1021/jacs.6b06021 ; Giant, Hollow 2D Metalloarchitecture: Stepwise Self-​Assembly of a Hexagonal Supramolecular Nut

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(4-[2,2':6',2''-terpyridin]-4'-ylphen-Boronic acid
(4-[2,2':6',2''-terpyridin]-4'-ylphen-Boronic acid