产品名称:1,4-bis(1,2,4-triazol-1-yl)butane其他名称:btb;1,1'-(1,4-Butanediyl)bis[1H-1,2,4-triazole] CAS:345952-55-8
结构信息
分子式 |
C8H12N6 |
分子量 |
192.22108 |
性状照片 |
|
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Cu6(btb)3(P2W18O62)]·2H2O [r2]; [Co(H2abtc)(4,4'-bipy)0.5(H2O)] [r4]; [Zn(mip)(btb)] [r5]
表征图谱
参考文献
1) Wang, Xin-Long; Qin, Chao; Wang, En-Bo; Su, Zhong-Min; Chem.- Eur. J. 2006, 12(10), 2680-2691, DOI: 10.1002/chem.200501242 ; Metal nuclearity modulated four-, six-, and eight-connected entangled frameworks based on mono-, bi-, and trimetallic cores as nodes
2) Tian, Ai-xiang; Ying, Jun; Peng, Jun; Sha, Jing-quan; Han, Zhan-gang; Ma, Jian-fang; Su, Zhong-min; Hu, Ning-hai; Jia, Heng-qing; Inorg. Chem. 2008, 47(8), 3274-3283, DOI: 10.1021/ic7023082 ; Assembly of the Highest Connectivity Wells-Dawson Polyoxometalate Coordination Polymer: the Use of Organic Ligand Flexibility
3) Tian, Ai-xiang; Ying, Jun; Peng, Jun; Sha, Jing-quan; Pang, Hai-jun; Zhang, Peng-peng; Chen, Yuan; Zhu, Min; Su, Zhong-min; Inorg. Chem. 2009, 48(1), 100-110, DOI: 10.1021/ic801338b ; Assemblies of Copper Bis(triazole) Coordination Polymers Using the Same Keggin Polyoxometalate Template
4) Zhao, Jun; Li, Dong-Sheng; Ke, Xi-Jun; Liu, Bin; Zou, Kun; Hu, Huai-Ming; Dalton Trans. 2012, 41(9), 2560-2563, DOI: 10.1039/c2dt12170k ; Auxiliary ligand-directed structural variation from 2D→3D polythreaded net to 3-fold interpenetrating 3D pillar-layered framework: Syntheses, crystal structures and magnetic properties
5) Han, Min-Le; Chang, Xin-Hong; Feng, Xun; Ma, Lu-Fang; Wang, Li-Ya; CrystEngComm 2014, 16(9), 1687-1695, DOI: 10.1039/c3ce41968a ; Temperature and pH driven self-assembly of Zn(II) coordination polymers: crystal structures, supramolecular isomerism, and photoluminescence