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1,4-bis(1,2,4-triazol-1-yl)butane
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1,4-bis(1,2,4-triazol-1-yl)butane
1,4-bis(1,2,4-triazol-1-yl)butane
CAS:345952-55-8 分子式:C8H12N6 分子量:192.22108
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产品名称:1,​4-​bis(1,​2,​4-​triazol-​1-​yl)​butane
其他名称:btb;1,​1'-​(1,​4-​Butanediyl)​bis[1H-​1,​2,​4-​triazole]
CAS:345952-55-8
结构信息
分子式 C8H12N6 分子量 192.22108
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Cu6(btb)​3(P2W18O62)​]​·2H2O [r2]; [Co(H2abtc)​(4,​4'-​bipy)​0.5(H2O)​] [r4]; [Zn(mip)​(btb)​]​ [r5]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Wang, Xin-Long; Qin, Chao; Wang, En-Bo; Su, Zhong-Min; Chem.- Eur. J. 2006, 12(10), 2680-2691, DOI: 10.1002/chem.200501242 ; Metal nuclearity modulated four-​, six-​, and eight-​connected entangled frameworks based on mono-​, bi-​, and trimetallic cores as nodes
2) Tian, Ai-xiang; Ying, Jun; Peng, Jun; Sha, Jing-quan; Han, Zhan-gang; Ma, Jian-fang; Su, Zhong-min; Hu, Ning-hai; Jia, Heng-qing; Inorg. Chem. 2008, 47(8), 3274-3283, DOI: 10.1021/ic7023082 ; Assembly of the Highest Connectivity Wells-​Dawson Polyoxometalate Coordination Polymer: the Use of Organic Ligand Flexibility
3) Tian, Ai-xiang; Ying, Jun; Peng, Jun; Sha, Jing-quan; Pang, Hai-jun; Zhang, Peng-peng; Chen, Yuan; Zhu, Min; Su, Zhong-min; Inorg. Chem. 2009, 48(1), 100-110, DOI: 10.1021/ic801338b ; Assemblies of Copper Bis(triazole) Coordination Polymers Using the Same Keggin Polyoxometalate Template
4) Zhao, Jun; Li, Dong-Sheng; Ke, Xi-Jun; Liu, Bin; Zou, Kun; Hu, Huai-Ming; Dalton Trans. 2012, 41(9), 2560-2563, DOI: 10.1039/c2dt12170k ; Auxiliary ligand-​directed structural variation from 2D→3D polythreaded net to 3-​fold interpenetrating 3D pillar-​layered framework: Syntheses, crystal structures and magnetic properties

5) Han, Min-Le; Chang, Xin-Hong; Feng, Xun; Ma, Lu-Fang; Wang, Li-Ya; CrystEngComm 2014, 16(9), 1687-1695, DOI: 10.1039/c3ce41968a ; Temperature and pH driven self-​assembly of Zn(II) coordination polymers: crystal structures, supramolecular isomerism, and photoluminescence

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1,4-bis(1,2,4-triazol-1-yl)butane
1,4-bis(1,2,4-triazol-1-yl)butane