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4,4'-(丁-1,3-二炔-1,4-二基)二苯胺
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4,4'-(丁-1,3-二炔-1,4-二基)二苯胺
4,4'-(buta-1,3-diyne-1,4-diyl)dianiline
CAS:30405-78-8 分子式:C16H12N2 分子量:232.27988
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产品名称:1,​4-​Bis(4-​aminophenyl)​butadiyne
其他名称:BDDA ; BDA;Aniline, 4,​4'-​butadiynylenedi-; 4,​4'-​(1,​3-​Butadiyne-​1,​4-​diyl)​bis[benzenamine]​; 4,​4'-​(Buta-​1,​3-​diyne-​1,​4-​diyl)​bis(benzenamine)
CAS:30405-78-8
结构信息
分子式 C16H12N2 分子量 232.27988
性状照片  
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料:TP-BDDA COF [r3]; NTU–BDA–HTA , NTU–BDA–DHTA [r4]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Wegner, Gerhard J. Polymer Sci. 1971, 9(2), 133-144, Topochemical reactions of monomers with conjugated triple bonds.  III.  Solid-​state reactivity of derivatives of diphenyldiacetylene
2) Deeming, Antony J.; Hogarth, Graeme; Lee, Mo-yin; Saha, Malini; Redmond, Simon P.; Phetmung, Hirihattaya; Orpen, A. Guy; Inorg. Chimi. Acta 2000, 309(1-2), 109-122, DOI: 10.1016/S0020-1693(00)00254-1 ; para-​Ethynyl aniline as a building block for fully π-​conjugated ligands and acetylide complexes: crystal structures of trans-​[Pt(PPh3)​2(C≡CC6H4NH2)​2] and [(μ-​H)​Ru3(CO)​9(μ-​C≡CC6H4NH2)​]
3) Pachfule, Pradip; Acharjya, Amitava; Roeser, Jerome; Langenhahn, Thomas; Schwarze, Michael; Schomaecker, Reinhard; Thomas, Arne; Schmidt, Johannes; Journal of the American Chemical Society 2018, 140(4), 1423-1427, DOI: 10.1021/jacs.7b11255 ; Diacetylene Functionalized Covalent Organic Framework (COF) for Photocatalytic Hydrogen Generation;

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4,4'-(丁-1,3-二炔-1,4-二基)二苯胺
4,4'-(丁-1,3-二炔-1,4-二基)二苯胺