CAS 30405-78-8|BDDA|BDA|CHEMSOON-MOF/COF材料专业供应商

产品名称：1,4-Bis(4-aminophenyl)butadiyne
其他名称：BDDA ; BDA;Aniline, 4,4'-butadiynylenedi-; 4,4'-(1,3-Butadiyne-1,4-diyl)bis[benzenamine]; 4,4'-(Buta-1,3-diyne-1,4-diyl)bis(benzenamine)
CAS：30405-78-8

结构信息

分子式	C16H12N2		分子量	232.27988
性状照片

性质说明

1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存

合成应用

1) 可作为单体用于合成COF材料：TP-BDDA COF [r3]; NTU–BDA–HTA , NTU–BDA–DHTA [r4]

表征图谱

HNMR

FTIR

HPLC

参考文献

1) Wegner, Gerhard J. Polymer Sci. 1971, 9(2), 133-144, Topochemical reactions of monomers with conjugated triple bonds. III. Solid-state reactivity of derivatives of diphenyldiacetylene

2) Deeming, Antony J.; Hogarth, Graeme; Lee, Mo-yin; Saha, Malini; Redmond, Simon P.; Phetmung, Hirihattaya; Orpen, A. Guy; Inorg. Chimi. Acta 2000, 309(1-2), 109-122, DOI: 10.1016/S0020-1693(00)00254-1 ; para-Ethynyl aniline as a building block for fully π-conjugated ligands and acetylide complexes: crystal structures of trans-[Pt(PPh3)2(C≡CC6H4NH2)2] and [(μ-H)Ru3(CO)9(μ-C≡CC6H4NH2)]

3) Pachfule, Pradip; Acharjya, Amitava; Roeser, Jerome; Langenhahn, Thomas; Schwarze, Michael; Schomaecker, Reinhard; Thomas, Arne; Schmidt, Johannes; Journal of the American Chemical Society 2018, 140(4), 1423-1427, DOI: 10.1021/jacs.7b11255 ; Diacetylene Functionalized Covalent Organic Framework (COF) for Photocatalytic Hydrogen Generation;

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