SIFSIX-1-Cu
SIFSIX-1-Cu
CAS:288297-89-2
分子式:C20H16CuF6N4Si
分子量:517.99
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品牌 / 纯度 / 包装
材料名称：SIFSIX-1-Cu
其他名称：[CuSiF6(4,4'-bpy)2].8H2O
CAS：288297-89-2
其他名称：[CuSiF6(4,4'-bpy)2].8H2O
CAS：288297-89-2
结构信息
| 单位分子式 | C20H8N4F6SiCu | 单位分子量 | 509.93 | ||
| 配位金属 | Cu | 配体 |
4,4'-联吡啶 4,4’-bipyridine (CAS：553-26-4) |
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| 孔径 | ~0.8nm | 孔容 | 0.55 cm3/g | ||
| 比表面 | NA | ||||
| 模拟结构 |   |
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产品性状
| 产品形貌 | 蓝色粉末 Blue Powders |
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| 粒径 | 不规则块状 | |||
稳定性
1) SIFSIX-1-Cu在有机溶剂（如甲醇）中较稳定
2) 热分解温度约150℃
2) 热分解温度约150℃
保存和活化方法
1) 常温或低温条件下，干燥密封保存
2) 建议使用前室温真空烘箱活化3小时
2) 建议使用前室温真空烘箱活化3小时
其他特性
荧光:NA
应用领域
1) 气体吸附与分离（如二氧化碳、二氧化硫等）
表征图谱
参考文献
1) Nugent, Patrick; Belmabkhout, Youssef; Burd, Stephen D.; Cairns, Amy J.; Luebke, Ryan; Forrest, Katherine; Pham, Tony; Ma, Shengqian; Space, Brian; Wojtas, Lukasz; Eddaoudi, Mohamed; Zaworotko, Michael J.; Nature 2013), 495(7439), 80-84, DOI: 10.1038/nature11893 ; Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation；
2）Xili Cui, Kaijie Chen, Huabin Xing, Qiwei Yang, Rajamani Krishna, Zongbi Bao, Hui Wu, Wei Zhou, Xinglong Dong, Yu Han, Bin Li, Qilong Ren, Michael J. Zaworotko, Banglin Chen. Science, 2016, 353, 6295, 141-145. DOI:10.1126/science.aaf2458. Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene【文献解读】；
3） Shin-ichiro Noro, Susumu Kitagawa, Mitsuru Kondo, Kenji Seki; Angewandte Chemie, International Edition (2000), 39(12), 2082-2084; https://doi.org/10.1002/1521-3773(20000616)39:12<2081::AID-ANIE2081>3.0.CO;2-A; A New, Methane Adsorbent, Porous Coordination Polymer [{CuSiF₆(4,4-bipyridine)₂}]ₙ【文献解读】；
4）Stephen D. Burd, Shengqian Ma, Jason A. Perman, Benjamin J. Sikora, Randall Q. Snurr, Praveen K. Thallapally, Jian Tian, Lukasz Wojtas, Michael J. Zaworotko, *Journal of the American Chemical Society*, 2012, 134, 3663-3666, DOI:10.1021/ja211340t, Paper title: Highly Selective Carbon Dioxide Uptake by [Cu(bpy-n)₂(SiF₆)] (bpy-1=4,4'-Bipyridine; bpy-2=1,2-Bis(4-pyridyl)ethene)【文献解读】；
5）Guining Chen, Cailing Chen, Yanan Guo, Zhenyu Chu, Yang Pan, Guozhen Liu, Gongping Liu, Yu Han, Wanqin Jin, Nanping Xu, *Science*, 2023, 381, 1350-1356, DOI:10.1126/science.adi1545, Paper title:Solid-solvent processing of ultrathin, highly loaded mixed-matrix membrane for gas separation【文献解读】；
6）Yang, L. F., Cui, X. L., Yang, Q. W., Qian, S. H., Wu, H., Bao, Z. B., Zhang, Z. G., Ren, Q. L., Zhou, W., Chen, B., Xing, H. B. (2018). Advanced Materials, 30(1), 1705374. DOI: 10.1002/adma.201705374; A Single-Molecule Propyne Trap: Highly Efficient Removal of Propyne from Propylene with Anion-Pillared Ultramicroporous Materials【文献解读】；
7) Daniel O’Nolan, Amrit Kumar, Michael J. Zaworotko*; Journal of the American Chemical Society, 2017, 139, 8508-8513; DOI：10.1021/jacs.7b01682; Water Vapor Sorption in Hybrid Pillared Square Grid Materials【文献解读】;
8) Katherine A. Forrest, Tony Pham, Brian Space;CrystEngComm, 2017, 19, 3338-3347;DOI ：10.1039/c7ce00594f;Comparing the mechanism and energetics of CO₂ sorption in the SIFSIX series【文献解读】；
