CAS 2485827-21-0|H8TPPE|CHEMSOON-MOF/COF材料专业供应商

产品名称：1,1,2,2-tetrakis[4-phosphonophenyl]ethylene
其他名称：H8TPPE;tetraphenylethylene tetraphosphonic acid
CAS：2485827-21-0

结构信息

分子式	C26H24O12P4		分子量	652.35676
性状照片

性质说明

1) 可溶于DMF、DMSO等
2) 室温密封保存

合成应用

1) 可作为配体用于合成MOF材料:[Ni2(H4TPPE)(H2O)6]·4H2O / CAU-46 , [Co2(H4TPPE)(H2O)4]·3H2O / CAU-47 [r1]; M-CAU-53 (M = Al3+, Ga3+, Fe3+) [r3];

表征图谱

HNMR

FTIR

HPLC

参考文献

1) Woehlbrandt, Stephan; Meier, Christoph; Reinsch, Helge; Svensson Grape, Erik; Inge, A. Ken; Stock, Norbert; Inorg. Chem. 2020, 59(18), 13343-13352, DOI: 10.1021/acs.inorgchem.0c01703 ; A Tetratopic Phosphonic Acid for the Synthesis of Permanently Porous MOFs: Reactor Size-Dependent Product Formation and Crystal Structure Elucidation via Three-Dimensional Electron Diffraction

2) Chakraborty, Debabrata; Ghorai, Arijit; Chowdhury, Avik; Banerjee, Susanta; Bhaumik, Asim; Chem.-Asian J. 2021, 16(12), 1562-1569, DOI: 10.1002/asia.202100270 ; A Tetradentate Phosphonate Ligand-based Ni-MOF as a Support for Designing High-performance Proton-conducting Materials

3) Steinke, Felix; Javed, Ali; Woehlbrandt, Stephan; Tiemann, Michael; Stock, Norbert; Dalton Trans. 2021, 50(38), 13572-13579, DOI: 10.1039/d1dt02610k ; New isoreticular phosphonate MOFs based on a tetratopic linker

4) Chakraborty, Debabrata; Bej, Sourav; Sahoo, Sumanta; Chongdar, Sayantan; Ghosh, Anirban; Banerjee, Priyabrata; Bhaumik, Asim; ACS Sustainable Chem. & Eng. 2021, 9(42), 14224-14237, DOI: 10.1021/acssuschemeng.1c04877 ; Novel Nanoporous Ti-Phosphonate Metal-Organic Framework for Selective Sensing of 2,4,6-Trinitrophenol and a Promising Electrode in an Energy Storage Device

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