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(4-(1,2,2-tris(4-phosphonophenyl)vinyl)phenyl)phosphonic acid
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(4-(1,2,2-tris(4-phosphonophenyl)vinyl)phenyl)phosphonic acid
CAS:2485827-21-0 分子式:C26H24O12P4 分子量:652.35676
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产品名称:1,​1,​2,​2-​tetrakis[4-​phosphonophenyl]​ethylene
其他名称:H8TPPE;tetraphenylethylene tetraphosphonic acid
CAS:2485827-21-0
结构信息
分子式 C26H24O12P4 分子量 652.35676
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Ni2(H4TPPE)​(H2O)​6]​·4H2O / CAU-​46 , [Co2(H4TPPE)​(H2O)​4]​·3H2O / CAU-​47 [r1]; M-​CAU-​53 (M = Al3+, Ga3+, Fe3+)​ [r3];
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Woehlbrandt, Stephan; Meier, Christoph; Reinsch, Helge; Svensson Grape, Erik; Inge, A. Ken; Stock, Norbert; Inorg. Chem. 2020, 59(18), 13343-13352, DOI: 10.1021/acs.inorgchem.0c01703 ; A Tetratopic Phosphonic Acid for the Synthesis of Permanently Porous MOFs: Reactor Size-​Dependent Product Formation and Crystal Structure Elucidation via Three-​Dimensional Electron Diffraction
2) Chakraborty, Debabrata; Ghorai, Arijit; Chowdhury, Avik; Banerjee, Susanta; Bhaumik, Asim; Chem.-Asian J. 2021, 16(12), 1562-1569, DOI: 10.1002/asia.202100270 ; A Tetradentate Phosphonate Ligand-​based Ni-​MOF as a Support for Designing High-​performance Proton-​conducting Materials
3) Steinke, Felix; Javed, Ali; Woehlbrandt, Stephan; Tiemann, Michael; Stock, Norbert; Dalton Trans. 2021, 50(38), 13572-13579, DOI: 10.1039/d1dt02610k ; New isoreticular phosphonate MOFs based on a tetratopic linker
4) Chakraborty, Debabrata; Bej, Sourav; Sahoo, Sumanta; Chongdar, Sayantan; Ghosh, Anirban; Banerjee, Priyabrata; Bhaumik, Asim; ACS Sustainable Chem. & Eng. 2021, 9(42), 14224-14237, DOI: 10.1021/acssuschemeng.1c04877 ; Novel Nanoporous Ti-​Phosphonate Metal-​Organic Framework for Selective Sensing of 2,​4,​6-​Trinitrophenol and a Promising Electrode in an Energy Storage Device

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(4-(1,2,2-tris(4-phosphonophenyl)vinyl)phenyl)phosphonic acid
(4-(1,2,2-tris(4-phosphonophenyl)vinyl)phenyl)phosphonic acid