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5-([2,2':6',2''-terpyridin]-4'-yl)isophthalic acid
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5-([2,2':6',2''-terpyridin]-4'-yl)isophthalic acid
5-([2,2':6',2''-terpyridin]-4'-yl)isophthalic acid
CAS:2226465-62-7 分子式:C23H15N3O4 分子量:397.3829
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产品名称:4'-​(3,​5-​Dicarboxyphenyl)​-​2,​2',​6',​2''-​terpyridine
其他名称:H2DATP ; H2-​DCPTP ; H2dtp;5-​[2,​2':6',​2''-​Terpyridin]​-​4'-​yl-​1,​3-​benzenedicarboxylic acid
CAS:2226465-62-7
结构信息
分子式 C23H15N3O4 分子量 397.3829
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Mn(DATP)​]​ [r1]; [Ln(DCPTP)​(NO3)​]​ [r2]; [Ni(dpt)​]​(H2O)​3 [r3]; [Ln(μ2-​OH)​(dtp)​(H2O)​] [Ln = Ho(III) and Tb(III)​] [r4]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Kang, Xiao-Min; Wang, Wen-Min; Yao, Lin-Hong; Ren, Hong-Xia; Zhao, Bin; Dalton Trans. 2018, 47(20), 6986-6994, DOI: 10.1039/C8DT01103F ; Solvent-​dependent variations of both structure and catalytic performance in three manganese coordination polymers
2) eng, Xin-Wen; Liu, Qing-Yan; Wang, Hui-Hong; Wang, Yu-Ling; Dyes and Pigments 2019, 162, 405-411, DOI: 10.1016/j.dyepig.2018.10.055 ; Eu(III)​- and Tb(III)​-​coordination polymer luminescent thermometers constructed from a π-​rich aromatic ligand exhibiting a high sensitivity
3) Mao, Hua-Jie; Chen, Qi-Xin; Han, Bin; Australian J. Chemistry. 2018, 71(11), 902-906, DOI: 10.1071/ch18274 ; Two Metal-​Organic Coordination Polymers Based on Polypyridyl Ligands: Crystal Structures and Inhibition of Human Spinal Tumour Cells
4) Xiong, Ying; Gao, Yun; Guo, Xiangguang; Wang, Yanliang; Su, Xiang; Sun, Xiaoqi; ACS Sustainable Chem. Eng. 2019, 7, 3, 3120-3126, DOI: 10.1021/acssuschemeng.8b04875 ; Water-​Stable Metal-​Organic Framework Material with Uncoordinated Terpyridine Site for Selective Th(IV)​/Ln(III) Separation

5) Kang, Xiao-Min; Yao, Lin-Hong; Jiao, Zhuo-Hao; Zhao, Bin; Chem.- Asian J. 2019, 14(20), 3668-3674, DOI: 10.1002/asia.201900712 ; Two Stable Heterometal-​MOFs as Highly Efficient and Recyclable Catalysts in the CO2 Coupling Reaction with Aziridines

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5-([2,2':6',2''-terpyridin]-4'-yl)isophthalic acid
5-([2,2':6',2''-terpyridin]-4'-yl)isophthalic acid