HKUST-1
HKUST-1
CAS:222404-02-6
分子式:C18H12Cu3O15
分子量:658.92
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材料名称：HKUST-1
其他名称：Cu-BTC; BASOLite C300；MOF-199
CAS：222404-02-6
其他名称：Cu-BTC; BASOLite C300；MOF-199
CAS：222404-02-6
结构信息
| 单位分子式 | C18H9O15Cu3 | 单位分子量 | 655.89 | ||
| 配位金属 | Cu | 配体 | 均苯三酸（CAS：554-95-0） | ||
| 孔径 | 0.9nm | 孔容 | 0.33 cm3/g | ||
| 比表面 | BET比表面1500 m2/g | ||||
| 模拟结构 |   |
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产品性状
| 产品形貌 | 蓝色粉末 Blue Powder |
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| 粒径 | 100-200nm; 500nm; 1um; 5um | |||
稳定性
1) HKUST-1在空气中较稳定，在潮湿空气和水溶液中逐渐分解。（如需要耐湿水稳定的HKUST-1/Cu-BTC结构，请参见Cu-BTC-IPA ）
2）热分解温度约240℃
2）热分解温度约240℃
保存和活化方法
1) 常温或低温条件下，干燥密封保存
2) 建议使用前150度（真空）烘箱活化3小时
2) 建议使用前150度（真空）烘箱活化3小时
其他特性
荧光:NA
应用领域
1) 气体（如二氧化碳）和污染物吸附
2) 具有开放的不饱和Cu金属位点，具有良好的催化性能
2) 具有开放的不饱和Cu金属位点，具有良好的催化性能
表征图谱
参考文献
1）Stephen S.-Y. Chui, Samuel M.-F. Lo, Jonathan P. H. Charmant, A. Guy Orpen and Ian D. Williams; Science 283 (5405), 1148-1150；
2）Zhang, W., Hu, Y. L., Ge, J., Jiang, H. L., & Yu, S. H. (2014); Journal of the American Chemical Society, 136(49), 16978-16981; DOI: 10.1021/ja509960n; A Facile and General Coating Approach to Moisture/Water-Resistant Metal-Organic Frameworks with Intact Porosity.【文献解读】;
3) Fei Ke, Yu-Peng Yuan, Ling-Guang Qiu*, Yu-Hua Shen, An-Jian Xie, Jun-Fa Zhu, Xing-You Tian, Li-De Zhang; Journal of Materials Chemistry, 2011, 21, 3843; DOI: 10.1039/c0jm01770a; Facile fabrication of magnetic metal–organic framework nanocomposites for potential targeted drug delivery.【文献解读】;
4) Bo Xiao, Paul S. Wheatley, Xuebo Zhao, Ashleigh J. Fletcher, Sarah Fox, Adriano G. Rossi, Ian L. Megson, S. Bordiga, L. Regli, K. Mark Thomas, Russell E. Morris; J. AM. CHEM. SOC. 2007, 129, 1203-1209 9 1203; DOI: 10.1021/ja066098k; High-Capacity Hydrogen and Nitric Oxide Adsorption and Storage in a Metal-Organic Framework.【文献解读】;
5) Biemmi E, Scherb C, Bein T. J. Am. Chem. Soc., 2007, 129, 26, 8054–8055. DOI: 10.1021/ja0701208. Oriented Growth of the Metal Organic Framework Cu₃(BTC)₂(H₂O)₃·xH₂O Tunable with Functionalized Self-Assembled Monolayers.【文献解读】;
6) Fei Ke, Ling-Guang Qiu, Yu-Peng Yuan, Fu-Min Peng, Xia Jiang, An-Jian Xie, Yu-Hua Shen, Jun-Fa Zhu; Journal of Hazardous Materials (2011), 196, 36-43; DOI：10.1016/j.jhazmat.2011.08.069; Thiol-functionalization of metal-organic framework by a facile coordination-based postsynthetic strategy and enhanced removal of Hg²⁺ from water【文献解读】；
7）Jie Song, Zhen Luo, David K. Britt, Hiroyasu Furukawa, Omar M. Yaghi, Kenneth I. Hardcastle, Craig L. Hill; J. Am. Chem. Soc., 2011, 133, 16839–16846; DOI: 10.1021/ja203695h; A Multiunit Catalyst with Synergistic Stability and Reactivity: A Polyoxometalate-Metal Organic Framework for Aerobic Decontamination【文献解读】
