产品名称:Biphenyl-2,2',4,4'-tetracarboxylic acid其他名称:2,4-H2bptc;[1,1'-Biphenyl]-2,2',4,4'-tetracarboxylic acid CAS:206647-35-0
结构信息
分子式 |
C16H10O8 |
分子量 |
330.2458 |
性状照片 |
|
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Zn2(2,4-bptc)(2,2'-bpy)] [r2]; [Mn(H2bptc)] [r3]
表征图谱
参考文献
1) Pryor, Kent E.; Shipps, W., Jr.; Skyler, David A.; Rebek, Julius, Jr.; Tetrahedron 1998, 54(16), 4107-4124, DOI: 10.1016/S0040-4020(98)00139-2 ; The activated core approach to combinatorial chemistry: a selection of new core molecules
2) Jia, Juan; Shao, Min; Jia, Tiantian; Zhu, Shourong; Zhao, Yongmei; Xing, Feifei; Li, Mingxing; CrystEngComm 2010, 12(5), 1548-1561, DOI: 10.1039/b916984a ; Coordination polymers of biphenyl-2,4,2',4'-tetracarboxylic acid-synthesis, structures and adsorption properties
3) Pan, Zhao-Rui; Xu, Jiao; Yao, Xiao-Qiang; Li, Yi-Zhi; Guo, Zi-Jian; Zheng, He-Gen; CrystEngComm 2011, 13(5), 1617-1624, DOI: 10.1039/C0CE00490A ; Syntheses, structures, magnetic and photoluminescence properties of metal-organic frameworks based on aromatic polycarboxylate acids
4) Wang, Feng; Ke, Xiaohuan; Zhao, Jinbo; Deng, Kejian; Leng, Xiaoke; Tian, Zhengfang; Wen, Lili; Li, Dongfeng; Dalton Trans. 2011, 40(44), 11856-11865, DOI: 10.1039/c1dt11130b ; Six new metal-organic frameworks with multi-carboxylic acids and imidazole-based spacers: syntheses, structures and properties