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benzaldehyde, 3,3',3'',3'''-(1,2-ethenediylidene)tetrakis[6-hydroxy-
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benzaldehyde, 3,3',3'',3'''-(1,2-ethenediylidene)tetrakis[6-hydroxy-
3,3',3'',3'''-(1,2-ethenediylidene)tetrakis[6-hydroxy-benzaldehyde
CAS:2036328-15-9 分子式:C30H20O8 分子量:508.475
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产品名称: 3,3',3'',3'''-(1,2-ethenediylidene)tetrakis[6-hydroxy-benzaldehyde
其他名称: TPE-​4OH-​CHO
CAS: 2036328-15-9
结构信息
分子式  C30H20O8 分子量  508.475
性状照片  
性质说明
1) 溶于DCM、DMF、DMSO等
2) 2-8℃ 密封保存
合成应用
1) 可作为单体用于合成COF材料
2) 可作为前驱体合成各类TPE衍生物,如:poly(TPE-​BZ) ; TBIHPE
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Xiong, Jia-Bin; Feng, Hai-Tao; Sun, Jian-Ping; Xie, Wen-Zhao; Yang, Dong; Liu, Minghua; Zheng, Yan-Song1) Xiong, J.; Feng, H.; Sun, J.; Xie, W.; Yang, D.; Liu, M.; Zheng, Y.; J. Am. Chem. Soc. 2016, 138(36), 11469-11472, DOI: 10.1021/jacs.6b07087 ; The Fixed Propeller-Like Conformation of Tetraphenylethylene that Reveals Aggregation-Induced Emission Effect, Chiral Recognition, and Enhanced Chiroptical Property 
2) Xiong, J.; Yuan, Y.; Wang, L.; Sun, J.; Qiao, W.; Zhang, H.; Duan, M.; Wang, H.; Zhang, S.; Zheng, Y.;  Org. Lett 2018, 20(2), 373-376, DOI: 10.1021/acs.orglett.7b03662 ; Evidence for Aggregation-Induced Emission from Free Rotation Restriction of Double Bond at Excited State 
3) Qu, H.; Tang, X.; Wang, X.; Li, Z.; Huang, Z.; Zhang, H.; Tian, Z.; Cao, X.; Chem. Sci. 2018, 9(47), 8814-8818, DOI: 10.1039/C8SC03404D ; Chiral molecular face-rotating sandwich structures constructed through restricting the phenyl flipping of tetraphenylethylene
4) Yuan, Y.; Xiong, J.; Luo, J.; Hu, M.; Jiang, H.; Liu, M.; Zheng, Y.; J. Mater. Chem. C 2019, 7(27), 8236-8243, DOI: 10.1039/C9TC02134E ; The self-assembly and chiroptical properties of tetraphenylethylene dicycle tetracholesterol with an AIE effect
5) Samy, Maha Mohamed; Mohamed, Mohamed Gamal; Kuo, Shiao-Wei; Composites Science and Technology 2020, 199, 108360,DOI: 10.1016/j.compscitech.2020.108360
 ; Pyrene-​functionalized tetraphenylethylene polybenzoxazine for dispersing single-​walled carbon nanotubes and energy storage

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benzaldehyde, 3,3',3'',3'''-(1,2-ethenediylidene)tetrakis[6-hydroxy-
benzaldehyde, 3,3',3'',3'''-(1,2-ethenediylidene)tetrakis[6-hydroxy-