产品名称:N,N',N''-Tris(3-pyridyl)trimesic amide其他名称:TPB ; 3-TPB;Tri-3-pyridinyl-1,3,5-benzenetricarboxamide; N,N',N''-tris(3-pyridinyl)-1,3,5-benzenetricarboxamide CAS:201036-79-5
结构信息
分子式 |
C24H18N6O3 |
分子量 |
438.43812 |
性状照片 |
|
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:Hydrogen-bonded porous materials ; 分子笼 ; metal-org. polyhedra (MOP); [CuI(aas-TPB)] [r5]
表征图谱
参考文献
1) Palmans, Anja R. A.; Vekemans, Jef A. J. M.; Meijer, E. W.; Palmans, Anja R. A.; Kooijman, Huub; Spek, Anton L.; Chem. Commun. 1997, (22), 2247-2248, DOI: 10.1039/a705339h ; Hydrogen-bonded porous solid derived from trimesic amide
2) Moon, Dohyun; Kang, Sangmi; Park, Jaejoon; Lee, Kyungjae; John, Rohith P.; Won, Hosik; Seong, Gi Hun; Kim, Yang Sun; Kim, Ghyung Hwa; Rhee, Hakjune; Lah, Myoung Soo; Journal of the American Chemical Society 2006, 128(11), 3530-3531, DOI: 10.1021/ja060051h ; Face-Driven Corner-Linked Octahedral Nanocages: M6L8 Cages Formed by C3-Symmetric Triangular Facial Ligands Linked via C4-Symmetric Square Tetratopic PdII Ions at Truncated Octahedron Corners
3) Shi, Naien; Dong, Hao; Yin, Gui; Xu, Zheng; Li, Shuhua; Adv. Func. Mater. 2007, 17(11), 1837-1843, DOI: 10.1002/adfm.200600857 ; A smart supramolecular hydrogel exhibiting pH-modulated viscoelastic properties
4) Park, Jaejoon; Hong, Seunghee; Moon, Dohyun; Park, Mira; Lee, Kyungjin; Kang, Sangmi; Zou, Yang; John, Rohith P.; Kim, Ghyung Hwa; Lah, Myoung Soo; Inorg. Chem. 2007, 46(24), 10208-10213, DOI: 10.1021/ic7013623 ; Porous Metal-Organic Frameworks Based on Metal-Organic Polyhedra with Nanosized Cavities as Supramolecular Building Blocks: Two-Fold Interpenetrating Primitive Cubic Networks of [Cu6L8]12+ Nanocages
5) Wang, Xiaolu; Liu, Mengjia; Wang, Yuqing; Fan, Hongyan; Wu, Jie; Huang, Chao; Hou, Hongwei; Inorg. Chem. 2017, 56(21), 13329-13336, DOI: 10.1021/acs.inorgchem.7b02106 ; Cu(I) Coordination Polymers as the Green Heterogeneous Catalysts for Direct C-H Bonds Activation of Arylalkanes to Ketones in Water with Spatial Confinement Effect