1,2,3,4,5,6-六(4-溴苯基)苯
1,1':2',1''-Terphenyl, 4,4''-dibromo-3',4',5',6'-tetrakis(4-bromophenyl)-
CAS:19057-50-2
分子式:C42H24Br6
分子量:
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产品名称：1,2,3,4,5,6-Hexakis(4-bromophenyl)benzene
其他名称：1,2,3,4,5,6-六(4-溴苯基)苯;HHB;Hexakis(4-bromophenyl)benzene;m-Terphenyl, 4,4''-dibromo-2',4',5',6'-tetrakis(p-bromophenyl)-; 4,4''-Dibromo-3',4',5',6'-tetrakis(4-bromophenyl)-1,1':2',1''-terphenyl; 1,1':2',1''-Terphenyl, 4,4''-dibromo-3',4',5',6'-tetrakis(4-bromophenyl)-;
CAS：19057-50-2
其他名称：1,2,3,4,5,6-六(4-溴苯基)苯;HHB;Hexakis(4-bromophenyl)benzene;m-Terphenyl, 4,4''-dibromo-2',4',5',6'-tetrakis(p-bromophenyl)-; 4,4''-Dibromo-3',4',5',6'-tetrakis(4-bromophenyl)-1,1':2',1''-terphenyl; 1,1':2',1''-Terphenyl, 4,4''-dibromo-3',4',5',6'-tetrakis(4-bromophenyl)-;
CAS：19057-50-2
结构信息
| 分子式 | C42H24Br6 | 分子量 | 1008.06396 | ||
| 性状照片 |  |
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性质说明
1) 19057-50-2 可溶于DCM、DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为中间体用于合成MOF材料配体和COF材料单体
2) 作为单体合成各类POP材料(如：HPOP-1 HPOP-2 [r4])及其中间体
表征图谱
参考文献
1) Rathore, Rajendra; Burns, Carrie L.; Deselnicu, Mihaela I.; Org. Lett. 2001, 3(18), 2887-2890, DOI: 10.1021/ol0163474 ; Multiple-Electron Transfer in a Single Step. Design and Synthesis of Highly Charged Cation-Radical Salts
2) Wu, Jishan; Watson, Mark D.; Zhang, Li; Wang, Zhaohui; Muellen, Klaus; J. Am. Chem. Soc. 2004, 126(1), 177-186, DOI: DOI:10.1021/ja037519q ; Hexakis(4-iodophenyl)-peri-hexabenzocoronene - A Versatile Building Block for Highly Ordered Discotic Liquid Crystalline Materials
3)Rathore, Rajendra; Burns, Carrie L; Organic Syntheses 2005, 82, 30-33, DOI: 10.1002/0471264229.os082.05 ; Preparation of hexakis(4-bromophenyl)benzene (HBB)
4) Chen, Qi; Luo, Min; Wang, Tao; Wang, Jin-Xiang; Zhou, Ding; Han, Ying; Zhang, Chang-Shan; Yan, Chao-Guo; Han, Bao-Hang; Macromolecules 2011, 44(14), 5573-5577, DOI: 10.1021/ma200915f ; Porous Organic Polymers Based on Propeller-Like Hexaphenylbenzene Building Units
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