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4'-(4-carboxyphenyl)-[2,2':6',2"-terpyridine]-5,5"-dicarboxylic acid
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4'-(4-carboxyphenyl)-[2,2':6',2"-terpyridine]-5,5"-dicarboxylic acid
4'-(4-carboxyphenyl)-[2,2':6',2"-terpyridine]-5,5"-dicarboxylic acid
CAS:1887067-79-9 分子式:C24H15N3O6 分子量:441.392405748367
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产品名称:4'-​(4-​Carboxyphenyl)​[2,​2':6',​2''-​terpyridine]​-​5,​5''-​dicarboxylicacid
其他名称:H3TPY ; TPY;
CAS:1887067-79-9
结构信息
分子式 C24H15N3O6 分子量 441.3924
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:Fe‐TPY‐MOF [r1] ; PCN-308 [r3]
表征图谱
HNMR
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Cao, Lingyun; Lin, Zekai; Peng, Fei; Wang, Weiwei; Huang, Ruiyun; Wang, Cheng; Yan, Jiawei; Liang, Jie; Zhang, Zhiming; Zhang, Teng; Long, Lasheng; Sun, Junliang; Lin, Wenbin; Angewandte Chemie, International Edition 2016, 55(16), 4962-4966, DOI: 10.1002/anie.201512054 ; Self-​Supporting Metal-​Organic Layers as Single-​Site Solid Catalysts
2) Shi, Wenjie; Cao, Lingyun; Zhang, Hua; Zhou, Xin; An, Bing; Lin, Zekai; Dai, Ruihan; Li, Jianfeng; Wang, Cheng; Lin, Wenbin; Angewandte Chemie, International Edition 2017, 56(33), 9704-9709, DOI: 10.1002/anie.201703675 ; Surface Modification of Two-​Dimensional Metal-​Organic Layers Creates Biomimetic Catalytic Microenvironments for Selective Oxidation
3) Zhang, Yingmu; Li, Jialuo; Yang, Xinyu; Zhang, Peng; Pang, Jiandong; Li, Bao; Zhou, Hong-Cai; Chem. Commun. 2019, 55(14), 2023-2026, DOI: 10.1039/c8cc09491h ; A mesoporous NNN-​pincer-​based metal-​organic framework scaffold for the preparation of noble-​metal-​free catalysts
4) Guo, Ying; Shi, Wenjie; Yang, Huijuan; He, Quanfeng; Zeng, Zhongming; Ye, Jin-yu; He, Xinru; Huang, Ruiyun; Wang, Cheng; Lin, Wenbin; J. Am. Chem. Soc. 2019, 141(44), 17875-17883, DOI: 10.1021/jacs.9b09227 ; Cooperative Stabilization of the [Pyridinium-​CO2-​Co] Adduct on a Metal-​Organic Layer Enhances Electrocatalytic CO2 Reduction
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4'-(4-carboxyphenyl)-[2,2':6',2"-terpyridine]-5,5"-dicarboxylic acid
4'-(4-carboxyphenyl)-[2,2':6',2"-terpyridine]-5,5"-dicarboxylic acid