CAS 185252-69-1|H2mpba|Me2pzba|CHEMSOON-MOF/COF材料专业供应商

产品名称：4-(3,5-Dimethylpyrazol-1-yl)benzoic acid
其他名称：H2mpba ; Me2pzba;4-(3,5-Dimethyl-1H-pyrazol-4-yl)benzoic acid
CAS：185252-69-1

结构信息

分子式	C12H12N2O2		分子量	216.23588
性状照片

性质说明

1) 可溶于DMF、DMSO等
2) 室温密封保存

合成应用

1) 可作为配体用于合成MOF材料：[M4(μ4-O)(Me2pzba)3] (M = Co, Zn) [r2]; [Zn(Hmpba)2] [r4]

表征图谱

HNMR

FTIR

HPLC

参考文献

1) Foces-Foces, Concepcion; Cativiela, Carlos; Zurbano, Maria Mar; Sobrados, Isabel; Jagerovic, Nadine; Elguero, Jose; J. Chem. Crystallography 1996, 26(8), 579-584, DOI: 10.1007/BF01668419 ; Molecular structure of 4-(3,5-dimethylpyrazol-1-yl)benzoic acid trifluoroacetate

2) Heering, Christian; Boldog, Ishtvan; Vasylyeva, Vera; Sanchiz, Joaquin; Janiak, Christoph; CrystEngComm 2013, 15(45), 9757-9768, DOI: 10.1039/c3ce41426d ; Bifunctional pyrazolate-carboxylate ligands for isoreticular cobalt and zinc MOF-5 analogs with magnetic analysis of {Co4(μ4-O)} node

3) He, Chun-Ting; Liao, Pei-Qin; Zhou, Dong-Dong; Wang, Bao-Ying; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming; Chem. Sci. 2014, 5(12), 4755-4762, DOI: 10.1039/C4SC01505C ; Visualizing the distinctly different crystal-to-crystal structural dynamism and sorption behavior of interpenetration-direction isomeric coordination networks

4) Ye, Zi-Ming; He, Chun-Ting; Xu, Yan-Tong; Krishna, Rajamani; Xie, Yi; Zhou, Dong-Dong; Zhou, Hao-Long; Zhang, Jie-Peng; Chen, Xiao-Ming; Cryst. Growth & Des. 2017, 17(4), 2166-2171, DOI: 10.1021/acs.cgd.7b00100 ; A New Isomeric Porous Coordination Framework Showing Single-Crystal to Single-Crystal Structural Transformation and Preferential Adsorption of 1,3-Butadiene from C4 Hydrocarbons

185252-69-1-CS017758.pdf

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