产品名称:4,4',4'',4''',4'''',4'''''-(2,3,6,7,10,11-triphenylenehexayl)hexakisBenzoic acid, 其他名称:TP ; H6TPHB;Benzoic acid, 4,4',4'',4''',4'''',4'''''-(2,3,6,7,10,11-triphenylenehexayl)hexakis- CAS:1821122-35-3
结构信息
分子式 |
C60H36O12 |
分子量 |
948.92064 |
性状照片 |
|
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:hydrogen-bonded hexagonal network (H-HexNet): Tp-1 [r2]; BUT-46A-F [r3]
表征图谱
参考文献
1) Hisaki, Ichiro; Ikenaka, Nobuaki; Tohnai, Norimitsu; Miyata, Mikiji; Chemical Communications 2016, 52(2), 300-303, DOI: 10.1039/C5CC07690K ; Polymorphs of layered assemblies of hydrogen-bonded hexagonal networks caused by conformational frustration
2) Hisaki, Ichiro; Nakagawa, Shoichi; Ikenaka, Nobuaki; Imamura, Yutaka; Katouda, Michio; Tashiro, Motomichi; Tsuchida, Hiromu; Ogoshi, Tomoki; Sato, Hiroyasu; Tohnai, Norimitsu; Miyata, Mikiji; DOI: 10.1021/jacs.6b02968 ; A Series of Layered Assemblies of Hydrogen-Bonded, Hexagonal Networks of C3-Symmetric π-Conjugated Molecules: A Potential Motif of Porous Organic Materials
3) Zhang, Yong-Zheng; He, Tao; Kong, Xiang-Jing; Lv, Xiu-Liang; Wu, Xue-Qian; Li, Jian-Rong; ACS Applied Materials & Interfaces 2018, 10(33), 27868-27874, DOI: 10.1021/acsami.8b09333 ; Tuning Water Sorption in Highly Stable Zr(IV)-Metal-Organic Frameworks through Local Functionalization of Metal Clusters
4) Dai, Hongliang; Wang, Shuai; Hisaki, Ichiro; Nakagawa, Shoichi; Ikenaka, Nobuaki; Deng, Ke; Xiao, Xunwen; Zeng, Qingdao; Chemistry - An Asian Journal (2017), 12(19), 2558-2564, DOI: 10.1002/asia.201700749 ; On-Surface Self-Assembly of a C3-Symmetric π-Conjugated Molecule Family Studied by STM: Two-Dimensional Nanoporous Frameworks