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2,2''-dimethyl-[1,1':4',1''-Terphenyl]-4,4''-dicarboxylic acid
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2,2''-dimethyl-[1,1':4',1''-Terphenyl]-4,4''-dicarboxylic acid
2,2''-dimethyl-[1,1':4',1''-terphenyl]-4,4''-dicarboxylic acid
CAS:1807547-39-2 分子式:C22H18O4 分子量:346.37592
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产品名称:2,​2''-​Dimethyl[1,​1':4',​1''-​terphenyl]​-​4,​4''-​dicarboxylic acid
其他名称:H2Me2BPDC; DMTPDC;2,2″-dimethyl-[1,1′:4′,1″-terphenyl]-4,4″-dicarboxylic acid
CAS:1807547-39-2
结构信息
分子式 C22H18O4 分子量 346.37592
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:Cu2(DMTPDC)2(AzoBiPyB) [r2] ; U6-Me2BPDC-8 / Th6-Me2BPDC-8 [r4]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Yu, Xiaojuan; Wang, Zhengbang; Buchholz, Maria; Fuellgrabe, Nena; Grosjean, Sylvain; Bebensee, Fabian; Braese, Stefan; Woell, Christof; Heinke, Lars; Phys. Chem. Chem. Phys. 2015, 17(35), 22721-22725, DOI: 10.1039/C5CP03091A ; cis-​to-​trans isomerization of azobenzene investigated by using thin films of metal-​organic frameworks
2) Wang, Zhengbang; Mueller, Kai; Valasek, Michal; Grosjean, Sylvain; Braese, Stefan; Woell, Christof; Mayor, Marcel; Heinke, Lars; J. Phys. Chem. C 2018, 122(33), 19044-19050, DOI: 10.1021/acs.jpcc.8b05843 ; Series of Photoswitchable Azobenzene-​Containing Metal-​Organic Frameworks with Variable Adsorption Switching Effect
3) Grosjean, Sylvain; Hassan, Zahid; Woell, Christof; Braese, Stefan; Eur. J. Org. Chem. 2019, 2019(7), 1446-1460,
4) Ejegbavwo, Otega A.; Martin, Corey R.; Olorunfemi, Oyindamola A.; Leith, Gabrielle A.; Ly, Richard T.; Rice, Allison M.; Dolgopolova, Ekaterina A.; Smith, Mark D.; Karakalos, Stavros G.; Birkner, Nancy; Powell, Brian A.; Pandey, Shubham; Koch, Robert J.; Misture, Scott T.; Loye, Hans-Conrad zur; Phillpot, Simon R.; Brinkman, Kyle S.; Shustova, Natalia B.; J. Am. Chem. Soc. 2019, 141(29), 11628-11640, DOI: 10.1021/jacs.9b04737 ; Thermodynamics and Electronic Properties of Heterometallic Multinuclear Actinide-​Containing Metal-​Organic Frameworks with "Structural Memory"

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2,2''-dimethyl-[1,1':4',1''-Terphenyl]-4,4''-dicarboxylic acid
2,2''-dimethyl-[1,1':4',1''-Terphenyl]-4,4''-dicarboxylic acid