SIFSIX-3-Zn
SIFSIX-3-Zn
CAS:1804924-64-8
分子式:C8H8N4Zn.F6Si
分子量:367.65
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品牌 / 纯度 / 包装
材料名称：SIFSIX-3-Zn
其他名称：[Zn(pz)2(SiF6)]
CAS：1804924-64-8
结构信息
| 单位分子式 | C12H8N4SiF6Zn | 单位分子量 | 367.65 | ||
| 配位金属 | Zn | 配体 |
吡嗪 (pz) |
||
| 孔径 | ~3.8 Å | 孔容 | / | ||
| 比表面积 | 368 m²/g | ||||
| 模拟结构 | / | ||||
产品性状
| 产品形貌 | 黄色晶体 | |||
| 粒径 | / | |||
稳定性
1) 在水、乙醇等常见溶剂中稳定
2) 热稳定性可达300°C
2) 热稳定性可达300°C
保存和活化方法
1) 常温或低温条件下干燥密封保存
2) 使用前在室温下真空烘箱活化3小时
其他特性
荧光：NA
应用领域
1) 从烟气中高效捕获CO2
2) 对CO2的选择性吸附优于N2和水蒸气
3) 适用于工业气体分离应用
2) 对CO2的选择性吸附优于N2和水蒸气
3) 适用于工业气体分离应用
表征图谱
参考文献
1) Elsaidi, Sameh K.; Mohamed, Mona H.; Schaef, Herbert T.; Kumar, Amrit; Lusi, Matteo; Pham, Tony; Forrest, Katherine A.; Space, Brian; Xu, Wenqian; Halder, Gregory J.; Liu, Jun; Zaworotko, Michael J.; Thallapally, Praveen K.; Chem. Commun., 2015, 51, 15530–15533, DOI: 10.1039/c5cc06577a; Hydrophobic pillared square grids for selective removal of CO2 from simulated flue gas；
2) Gong, Heqing; Nguyen, Tien Hoa; Wang, Rong; Bae, Tae-Hyun; Journal of Membrane Science, 2015, 490, 108-117, DOI: 10.1016/j.memsci.2015.08.018; Separations of binary Mixtures of CO₂/CH₄ and CO₂/N₂ with mixed-matrix Membranes containing Zn(pyrz)₂(SiF₆) metal-organic framework;
2) Gong, Heqing; Nguyen, Tien Hoa; Wang, Rong; Bae, Tae-Hyun; Journal of Membrane Science, 2015, 490, 108-117, DOI: 10.1016/j.memsci.2015.08.018; Separations of binary Mixtures of CO₂/CH₄ and CO₂/N₂ with mixed-matrix Membranes containing Zn(pyrz)₂(SiF₆) metal-organic framework;
3) Nugent, Patrick; Belmabkhout, Youssef; Burd, Stephen D.; Cairns, Amy J.; Luebke, Ryan; Forrest, Katherine; Pham, Tony; Ma, Shengqian; Space, Brian; Wojtas, Lukasz; Eddaoudi, Mohamed; Zaworotko, Michael J.; Nature 2013), 495(7439), 80-84, DOI: 10.1038/nature11893 ; Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation【文献解读】；
4）Xili Cui, Kaijie Chen, Huabin Xing, Qiwei Yang, Rajamani Krishna, Zongbi Bao, Hui Wu, Wei Zhou, Xinglong Dong, Yu Han, Bin Li, Qilong Ren, Michael J. Zaworotko, Banglin Chen. Science, 2016, 353, 6295, 141-145. DOI:10.1126/science.aaf2458. Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene【文献解读】;
5) Yang, L. F., Cui, X. L., Yang, Q. W., Qian, S. H., Wu, H., Bao, Z. B., Zhang, Z. G., Ren, Q. L., Zhou, W., Chen, B., Xing, H. B. (2018). Advanced Materials, 30(1), 1705374. DOI: 10.1002/adma.201705374; A Single-Molecule Propyne Trap: Highly Efficient Removal of Propyne from Propylene with Anion-Pillared Ultramicroporous Materials【文献解读】；
6) Katherine A. Forrest, Tony Pham, Sameh K. Elsaidi, Mona H. Mohamed, Praveen K. Thallapally, Michael J. Zaworotko, Brian Space; Crystal Growth & Design, 2019, 19, 3732-3743; DOI：10.1021/acs.cgd.9b00086; Investigating CO₂ Sorption in SIFSIX-3-M (M = Fe, Co, Ni, Cu, Zn) through Computational Studies【文献解读】;
7) Katherine A. Forrest, Tony Pham, Brian Space;CrystEngComm, 2017, 19, 3338-3347;DOI ：10.1039/c7ce00594f;Comparing the mechanism and energetics of CO₂ sorption in the SIFSIX series【文献解读】；
