SIFSIX-3-Ni
SIFSIX-3-Ni
CAS:1801992-25-5
分子式:C8H8F6N4NiSi
分子量:360.95
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品牌 / 纯度 / 包装
材料名称：SIFSIX-3-Ni
其他名称：[Ni(pz)2(SiF6)]
CAS：1801992-25-5
基本信息
| 单位分子式 | C8H8F6N4NiSi | 单位分子量 | 360.95 | ||
| 配位金属 | Ni | 配体 |
吡嗪 (pz) |
||
| 孔径 | / | 孔容 | / | ||
| 比表面积 | 368 m²/g | ||||
| 模拟结构 | / | ||||
产品性状
| 产品形貌 | 蓝色粉末 | |||
| 粒径 | / | |||
稳定性
1) 在水、乙醇等常见溶剂中稳定
2) 热稳定性可达300°C
2) 热稳定性可达300°C
保存和活化方法
1) 常温或低温条件下干燥密封保存
2) 使用前在室温下真空烘箱活化3小时
其他特性
荧光：NA
应用领域
1) 从烟气中高效捕获CO2
2) 对CO2的选择性吸附优于N2和水蒸气
3) 适用于工业气体分离应用
2) 对CO2的选择性吸附优于N2和水蒸气
3) 适用于工业气体分离应用
表征图谱
参考文献
1) Elsaidi, Sameh K.; Mohamed, Mona H.; Schaef, Herbert T.; Kumar, Amrit; Lusi, Matteo; Pham, Tony; Forrest, Katherine A.; Space, Brian; Xu, Wenqian; Halder, Gregory J.; Liu, Jun; Zaworotko, Michael J.; Thallapally, Praveen K.; Chem. Commun., 2015, 51, 15530–15533, DOI: 10.1039/c5cc06577a; Hydrophobic pillared square grids for selective removal of CO2 from simulated flue gas;
2) Yang, L. F., Cui, X. L., Yang, Q. W., Qian, S. H., Wu, H., Bao, Z. B., Zhang, Z. G., Ren, Q. L., Zhou, W., Chen, B., Xing, H. B. (2018). Advanced Materials, 30(1), 1705374. DOI: 10.1002/adma.201705374; A Single-Molecule Propyne Trap: Highly Efficient Removal of Propyne from Propylene with Anion-Pillared Ultramicroporous Materials【文献解读】；
3）Jieyi Zheng, Xili Cui, Qiwei Yang, Qilong Ren, Yiwen Yang, Huabin Xing; Chemical Engineering Journal, 2018, 354, 1075-1082; DOI：10.1016/j.cej.2018.08.119; Shaping of ultrahigh-loading MOF pellet with a strongly anti-tearing binder for gas separation and storage【文献解读】;
4) Daniel O’Nolan, Amrit Kumar, Michael J. Zaworotko*; Journal of the American Chemical Society, 2017, 139, 8508-8513; DOI：10.1021/jacs.7b01682; Water Vapor Sorption in Hybrid Pillared Square Grid Materials【文献解读】;
5) Sameh K. Elsaidi, Mona H. Mohamed, Herbert T. Schaef, Amrit Kumar, Matteo Lusi, Tony Pham, Katherine A. Forrest, Brian Space, Wenqian Xu, Gregory J. Halder, Jun Liu, Michael J. Zaworotko, Praveen K. Thallapally; Chem. Commun., 2015, 51, 15530-15533; DOI code：10.1039/c5cc06577a; Hydrophobic pillared square grids for selective removal of CO₂ from simulated flue gas【文献解读】;
6) Valeriya Chernikova, Osama Shekhah, Youssef Belmabkhout, Mohamed Eddaoudi*; ACS Applied Nano Materials, 2020, 3, 6432-6439; DOI：10.1021/acsanm.0c00909; Nanoporous Fluorinated Metal-Organic Framework-Based Membranes for CO₂ Capture【文献解读】;
7) Katherine A. Forrest, Tony Pham, Sameh K. Elsaidi, Mona H. Mohamed, Praveen K. Thallapally, Michael J. Zaworotko, Brian Space; Crystal Growth & Design, 2019, 19, 3732-3743; DOI：10.1021/acs.cgd.9b00086; Investigating CO₂ Sorption in SIFSIX-3-M (M = Fe, Co, Ni, Cu, Zn) through Computational Studies【文献解读】
