PCN-250(Fe)
PCN-250(Fe)
CAS:1771755-22-6
分子式:C48H28Fe6N6O32
分子量:1535.83
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材料名称：PCN-250(Fe)
其他名称：MIL-127(Fe); Fe-soc-MOF; PCN-250(Fe3); Iron azobenzene tetracarboxylic
CAS：1771755-22-6 或 1257379-88-6
其他名称：MIL-127(Fe); Fe-soc-MOF; PCN-250(Fe3); Iron azobenzene tetracarboxylic
CAS：1771755-22-6 或 1257379-88-6
结构信息
| 单位分子式 | C48H18N6O32Fe6 | 单位分子量 | 1525.774 | ||
| 配位金属 | Fe | 配体 | 3,3’,5,5’-azobenzenetetracarboxylic（CAS：365549-33-3 ） | ||
| 孔径 | 1nm | 孔容 | 0.5 cm3/g | ||
| 比表面 | BET比表面 1200-1400 m2/g | ||||
| 模拟结构 |   |
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产品性状
| 产品形貌 | 红棕色粉末 Dark red Crystals |
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| 粒径 | ||||
稳定性
1) PCN-250在空气中稳定，在水溶液和弱碱性条件下较稳定
2) 热分解温度大于300℃
2) 热分解温度大于300℃
保存和活化方法
1) 常温或低温条件下，干燥密封保存
2) 建议使用前150度（真空）烘箱活化3小时
2) 建议使用前150度（真空）烘箱活化3小时
其他特性
荧光:NA
应用领域
1) 气体（如二氧化碳）和污染物吸附
2) Fe作为路易斯酸催化剂具有良好的催化性能
2) Fe作为路易斯酸催化剂具有良好的催化性能
表征图谱
参考文献
1) D. W. Feng, K. C. Wang, Z. W. Wei, Y. P. Chen, C. M. Simon, R. K. Arvapally, R. L. Martin, M. Bosch, T. F. Liu, S. Fordham, D. Q. Yuan, M. A. Omary, M. Haranczyk, B. Smit, H. C. Zhou, Nat. Commun. 2014, 5, 5723. DOI: 10.1038/ncomms6723 (2014) ; Kinetically tuned dimensional augmentation as a versatile synthetic route towards robust metal–organic frameworks
2) A. Dhakshinamoorthy, M.Alvaro, H.Chevreau, P. Horcajada, T.Devic, C. Serre and H. Garcia, Catal. Sci. Technol., 2012,2, 324-330, DOI: 10.1039/C2CY00376G ; Iron(iii) metal–organic frameworks as solid Lewis acids for the isomerization of α-pinene oxide;
3) Wen-Juan Zhang, Xiao-Qin Liu, Lin-Bing Sun, Li Zheng, Shi-Chao Qi, Jia-Xin Li, Ding-Ming Xue； Journal of Materials Chemistry A, 2023, 11, 17484–17490； DOI: 10.1039/d3ta01241g； Maintaining the configuration of a light-responsive metal-organic framework: LiYGeO₄:Bi³⁺-incorporation-induced long-term bending through short-time light irradiation【文献解读】;
4) Jing Zhang, Frederic Dumur, Patricia Horcajada, Carine Livage, Pu Xiao, Jean Pierre Fouassier, Didier Gigmes, Jacques Lalevée,；Macromolecular Chemistry and Physics, 2016；DOI: 10.1002/macp.201600352；Iron-Based Metal-Organic Frameworks (MOF) as Photocatalysts for Radical and Cationic Polymerizations under Near UV and Visible LEDs (385–405 nm)【文献解读】;
5) Zhijie Chen, Xingjie Wang, Ran Cao, Karam B. Idrees, Xinyao Liu, Megan C. Wasson, Omar K. Farha’;ACS Materials Letters, 2020, 2, 1129−1134; DOI: 10.1021/acsmaterialslett.0c00264; Water-Based Synthesis of a Stable Iron-Based Metal−Organic Framework for Capturing Toxic Gases【文献解读】;
6) Hannah F. Drake, Sayan Banerjee, Jialuo Li, Zachary T. Perry, Angelo Kirchon, Osman K. Ozdemir, Paul A. Lindahl, Hong-Cai Zhou, Gregory S. Day, Shaik Waseem Vali, Zhifeng Xiao, Elizabeth A. Joseph, Jason E. Kuszynski; ChemComm, 2019, 55, 12769—12772; DOI: 10.1039/c9cc04555d; The thermally induced decarboxylation mechanism of a mixed-oxidation state carboxylate-based iron metal–organic framework【文献解读】；
7）Tatiya Chokbunpiam, Siegfried Fritzsche, Vudhichai Parasuk, Jürgen Caro, Suttichai Assabumrungrat; Chemical Physics Letters, 2018; DOI: 10.1016/j.cplett.2018.02.032; Molecular simulations of a CO₂/CO mixture in MIL-127【文献解读】
